4. Cobalt phosphate (Cos(PO4)2, 15.38 g. 366.75 g/mol) and chromium(III) chloride (CrCl3, 3.46 g, 158.35 g/mol) were added to enough water to make a 100 mL solution. When equilibrium was reached, the equilibrium concentration of cobalt(I) was [Co¹*]eq = 0.0172 M. Co2+ (aq) + Cr³+ (2 (aq) K₁ K.1 co (aa) + Cr4+ (aq) K 1.184 x 103 a. Calculate the equilibrium concentrations of the ions in the reaction. b. The equilibrium was stressed by adding chromium(IV) oxide (CrO₂, 2.134 g. 84.00 g/mol) to the solution. Determine the concentration of Co" after equilibrium was re-established. (Assume no change in solution volume with the CrO₂ addition.)

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Chapter12: Chemical Equilibrium
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4. Cobalt phosphate (CO3(PO4)2, 15.38 g, 366.75 g/mol) and chromium(III) chloride (CrCl3, 3.46 g,
158.35 g/mol) were added to enough water to make a 100 mL solution. When equilibrium was reached,
the equilibrium concentration of cobalt(I) was [Co¹*Jeq = 0.0172 M.
Co2+ (aq) + Cr³+ (aq)
K₁
K-1
Co¹+
(aq) + Cr4+
(aq)
K. = 1.184 x 10-3
a. Calculate the equilibrium concentrations of the ions in the reaction.
b. The equilibrium was stressed by adding chromium(IV) oxide (CrO2, 2.134 g, 84.00 g/mol) to the
solution. Determine the concentration of Co¹ after equilibrium was re-established. (Assume no change
in solution volume with the CrO₂ addition.)
Transcribed Image Text:4. Cobalt phosphate (CO3(PO4)2, 15.38 g, 366.75 g/mol) and chromium(III) chloride (CrCl3, 3.46 g, 158.35 g/mol) were added to enough water to make a 100 mL solution. When equilibrium was reached, the equilibrium concentration of cobalt(I) was [Co¹*Jeq = 0.0172 M. Co2+ (aq) + Cr³+ (aq) K₁ K-1 Co¹+ (aq) + Cr4+ (aq) K. = 1.184 x 10-3 a. Calculate the equilibrium concentrations of the ions in the reaction. b. The equilibrium was stressed by adding chromium(IV) oxide (CrO2, 2.134 g, 84.00 g/mol) to the solution. Determine the concentration of Co¹ after equilibrium was re-established. (Assume no change in solution volume with the CrO₂ addition.)
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