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4) Intramolecular Claisen condensation is called a) Cannizaro b) Dickmann c) Mannich 5) propanoic acid can be prepared from reaction - 3) H₂O, heat/-CO₂ a) diethyl malonate b) ethyl acetoacetate c) diethyl acetate reaction ---- with 1) EtONa 2) CH₁-Br

4) Intramolecular Claisen condensation is called a) Cannizaro b) Dickmann c) Mannich 5) propanoic acid can be prepared from reaction - 3) H₂O, heat/-CO₂ a) diethyl malonate b) ethyl acetoacetate c) diethyl acetate reaction ---- with 1) EtONa 2) CH₁-Br

Organic Chemistry
Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter22: Carbonyl Alpha-substitution Reactions
Section22.SE: Something Extra
Problem 64AP: The key step in a reported laboratory synthesis of sativene, a hydrocarbon isolated from the mold...
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- reaction 4) Intramolecular Claisen condensation is called a) Cannizaro b) Dickmann c) Mannich with 1) EtONa 5) propanoic acid can be prepared from reaction 3) H₂O, heat / -CO₂ a) diethyl malonate b) ethyl acetoacetate c) diethyl acetate 1) OH ? 6) Cyclohexanone + O 2) H1-H₂O a) allyl methyl ketone b) methyl vinyl ketone c) allyl vinyl ketone CH3 7) acetone + ? CHO-CC-CHO CH3 CH3 CH3 a) CH3-C-PPh3 b) CH3--PPh3 c) CH3-C PPh3 CH3 8) The product of Claisen condensation is a) a-keto ester b) B-keto ester c) 8-keto ester 9) reaction of cyclohexanone with formaldehyde and dimethyl amine in Mannich reaction give -CH3 CH3 -CH3 CH3 b) CH3 C) CH3 10) 2 mole 2-methyl cyclopentanone CH3 CH3 a) b) 11) ОН b) ? Na OEt CH3 c) 2- ? CH3 c) 2) CH3-Br CH3 CH3
Transcribed Image Text:- reaction 4) Intramolecular Claisen condensation is called a) Cannizaro b) Dickmann c) Mannich with 1) EtONa 5) propanoic acid can be prepared from reaction 3) H₂O, heat / -CO₂ a) diethyl malonate b) ethyl acetoacetate c) diethyl acetate 1) OH ? 6) Cyclohexanone + O 2) H1-H₂O a) allyl methyl ketone b) methyl vinyl ketone c) allyl vinyl ketone CH3 7) acetone + ? CHO-CC-CHO CH3 CH3 CH3 a) CH3-C-PPh3 b) CH3--PPh3 c) CH3-C PPh3 CH3 8) The product of Claisen condensation is a) a-keto ester b) B-keto ester c) 8-keto ester 9) reaction of cyclohexanone with formaldehyde and dimethyl amine in Mannich reaction give -CH3 CH3 -CH3 CH3 b) CH3 C) CH3 10) 2 mole 2-methyl cyclopentanone CH3 CH3 a) b) 11) ОН b) ? Na OEt CH3 c) 2- ? CH3 c) 2) CH3-Br CH3 CH3
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