= 378g d. The specific heat of the resulting solution is 3.87 J/g °C. If the temperature change was measured to be 20.8°C, how many joules did the solution absorb? e. How many joules did the calorimeter absorb? f. Calculate the total number of joules released by the reaction. g. Calculate AH neutralization in kJ/mol.

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Chapter1: Chemical Foundations
Section: Chapter Questions
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3. Using the same calorimeter as in problem 2, a student mixed 180.0 mL of 2.50 M HNO3 with
180.0 mL of 2.55 M KOH.
a. Write the neutralization reaction occurring.
HNO3 + KOH
KNO3
+ H2O
1>
b. What is the final volume of the solution? What is its concentration (of the salt produced)?
nal Vol
IB0.OML + 180mL)
360ML
#ofmales
=V XM
of HNg= 180mb x 2.50M
1000 m
= 0.45mol
#ofmolesof = 180mL
1000 mYL
of
KOH
x 2.55M
=0.46 mol
0.45mol XI000=1-25 (M
360ML
Ho
Lonc =
c. If the density of the resulting solution is 1.05 g/mL, what is the mass of the resulting.
С.
solution?
mass= Density x Volume
= 1.05g/mx 360m
378g
d. The specific heat of the resulting solution is 3.87 J/g•°C. If the temperature change was
measured to be 20.8°C, how many joules did the solution absorb?
е.
How many joules did the calorimeter absorb?
f. Calculate the total number of joules released by the reaction.
g.
Calculate AH neutralization in kJ/mol.
64 EXPERIMENT 2
Transcribed Image Text:3. Using the same calorimeter as in problem 2, a student mixed 180.0 mL of 2.50 M HNO3 with 180.0 mL of 2.55 M KOH. a. Write the neutralization reaction occurring. HNO3 + KOH KNO3 + H2O 1> b. What is the final volume of the solution? What is its concentration (of the salt produced)? nal Vol IB0.OML + 180mL) 360ML #ofmales =V XM of HNg= 180mb x 2.50M 1000 m = 0.45mol #ofmolesof = 180mL 1000 mYL of KOH x 2.55M =0.46 mol 0.45mol XI000=1-25 (M 360ML Ho Lonc = c. If the density of the resulting solution is 1.05 g/mL, what is the mass of the resulting. С. solution? mass= Density x Volume = 1.05g/mx 360m 378g d. The specific heat of the resulting solution is 3.87 J/g•°C. If the temperature change was measured to be 20.8°C, how many joules did the solution absorb? е. How many joules did the calorimeter absorb? f. Calculate the total number of joules released by the reaction. g. Calculate AH neutralization in kJ/mol. 64 EXPERIMENT 2
EXPERIMENT 2: DETERMINING THE CHANGE IN ENTHALPY OF A REACTION
QUESTIONS
1. Why is the concentration of the base used greater than the concentration of the acid?
The conc of the base is greater thon the concentration of the
acid in order to ensure thot all of the acid reacts
2. In a similar experiment, a student mixed 200.0 mL of hot water with 200.0 mL of cool water. The
temperature change for the hot water was 26.5°C and the temperature change for the cool water
was 24.2°C.
AT 26. 5°C
H.
AT= 24.2 C
%3D
a.
Calculate the joules lost by the hot water.
=m CSAT
= 200.09
= - 22175.2J
= -22.175KJ
X 4.184 J/g°C x (-26.5°C)
%3D
b. Calculate the joules absorbed by the cool water.
Q=mCs AT
:200.09 x 4.1845lg °C x 24.2 °C
= 20. 251 KJ
%3D
Calculate the joules absorbed by the calorimeter.
%3D
= 22.175 - 20.251
=D1.924KJ
%3D
d. Calculate the calorimeter constant.
(1.924x103)
79.5J/°C
%3D
ATC
(24.2
C.
Transcribed Image Text:EXPERIMENT 2: DETERMINING THE CHANGE IN ENTHALPY OF A REACTION QUESTIONS 1. Why is the concentration of the base used greater than the concentration of the acid? The conc of the base is greater thon the concentration of the acid in order to ensure thot all of the acid reacts 2. In a similar experiment, a student mixed 200.0 mL of hot water with 200.0 mL of cool water. The temperature change for the hot water was 26.5°C and the temperature change for the cool water was 24.2°C. AT 26. 5°C H. AT= 24.2 C %3D a. Calculate the joules lost by the hot water. =m CSAT = 200.09 = - 22175.2J = -22.175KJ X 4.184 J/g°C x (-26.5°C) %3D b. Calculate the joules absorbed by the cool water. Q=mCs AT :200.09 x 4.1845lg °C x 24.2 °C = 20. 251 KJ %3D Calculate the joules absorbed by the calorimeter. %3D = 22.175 - 20.251 =D1.924KJ %3D d. Calculate the calorimeter constant. (1.924x103) 79.5J/°C %3D ATC (24.2 C.
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