34. Hot and spicy foods contain molecules that stimulate pain-detecting nerve endings. Two such molecules are piperine and capsaicin: H H - CH=CH_CH=CH- H. H. H. Piperine H,CO, „CH2. CH2 NI (CH,), / CH CH CH, HO `H H `CH, Capsaicin Piperine is the active compound in white and black pepper, and capsaicin is the active compound in chili peppers. The ring struc- tures in piperine and capsaicin are shorthand notation. Each point where lines meet represents a carbon atom. a. Complete the Lewis structure for piperine and capsaicin show- ing all lone pairs of electrons. h. How many carbon atoms are sp, sp², and sp'hybridized in each molecule? c. Which hybrid orbitals are used by the nitrogen atoms in each molecule?

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34. Hot and spicy foods contain molecules that stimulate pain-detecting
nerve endings. Two such molecules are piperine and capsaicin:
нн
H
H
- CH=CH_CH=CH-
H.
Ö H H
нн
H.
Piperine
H;CO.
CH &
CH
CH3
(CH,), j CH
CH,
НО
H.
Capsaicin
Piperine is the active compound in white and black pepper, and
capsaicin is the active compound in chili peppers. The ring struc-
tures in piperine and capsaicin are shorthand notation. Each point
where lines meet represents a carbon atom.
a. Complete the Lewis structure for piperine and capsaicin show-
ing all lone pairs of electrons.
b. How many carbon atoms are sp, sp², and sp' hybridized in each
molecule?
e. Which hybrid orbitals are used by the nitrogen atoms in each
molecule?
d. Give approximate values for the bond angles marked a through
I in the above structures.
Transcribed Image Text:34. Hot and spicy foods contain molecules that stimulate pain-detecting nerve endings. Two such molecules are piperine and capsaicin: нн H H - CH=CH_CH=CH- H. Ö H H нн H. Piperine H;CO. CH & CH CH3 (CH,), j CH CH, НО H. Capsaicin Piperine is the active compound in white and black pepper, and capsaicin is the active compound in chili peppers. The ring struc- tures in piperine and capsaicin are shorthand notation. Each point where lines meet represents a carbon atom. a. Complete the Lewis structure for piperine and capsaicin show- ing all lone pairs of electrons. b. How many carbon atoms are sp, sp², and sp' hybridized in each molecule? e. Which hybrid orbitals are used by the nitrogen atoms in each molecule? d. Give approximate values for the bond angles marked a through I in the above structures.
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