34. Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (#) must show two products. H. HBr (a)* Br HBr (b) (1.00 equiv.) Br HBr (c)
34. Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (#) must show two products. H. HBr (a)* Br HBr (b) (1.00 equiv.) Br HBr (c)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![The image presents a question involving organic chemistry reactions, specifically focusing on drawing the major organic product(s) for a series of reactions. It emphasizes including correct stereochemistry where indicated by an asterisk (*), and reactions marked by a double dagger (‡) must show two products.
Here's a transcription and brief description of each reaction:
1. **Reaction (a)*:**
- Reactant: An alkene
- Reagent: HBr
- Product: Alkyl bromide with specified stereochemistry, showing a bromine atom (Br) addition.
2. **Reaction (b)‡:**
- Reactant: An alkene
- Reagent: HBr (1.00 equiv.)
- Products: Two different alkyl bromides, illustrating the formation of both possible regioisomers.
3. **Reaction (c)*:**
- Reactant: Phenyl-substituted alkene
- Reagent: HBr
- Product: Alkyl bromide with specified configuration, displaying addition of both bromine (Br) and hydrogen (H) atoms.
4. **Reaction (d):**
- Reactant: Cyclohexene derivative
- Reagent: HCl
- Product: Chloro-cyclohexane derivative.
5. **Reaction (e):**
- Reactant: Cyclohexene derivative
- Reagent: 48% wt. HBr
- Condition: Heat (Δ)
- Product: Alkyl bromide product.
6. **Reaction (f)*:**
- Reactant: Tetramethylcyclobutene
- Reagent: 37% wt. HCl
- Condition: Heat
- Product: Chlorinated cyclobutene with specified stereochemistry.
7. **Reaction (g):**
- Reactant: Diene
- Reagent: [H₂SO₄ / H₂O]
- Product: Methanol adduct with an oxygen-containing functional group (OCH₃).
8. **Reaction (h):**
- Reactant: Substituted alkene with a wedge bond
- Reagent: [H₂SO₄ / Δ] with excess CH₃OH
- Product: Methoxy-alkane derivative reflecting specific stereochemistry.
9. **Reaction (i)*:**
- Reactant: Phenyl-sub](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F37553829-9acc-4d6b-9a63-37f3687d9d71%2Fc9eba531-011c-4687-9a5e-b06f3265d920%2Fcipyksg_processed.jpeg&w=3840&q=75)
Transcribed Image Text:The image presents a question involving organic chemistry reactions, specifically focusing on drawing the major organic product(s) for a series of reactions. It emphasizes including correct stereochemistry where indicated by an asterisk (*), and reactions marked by a double dagger (‡) must show two products.
Here's a transcription and brief description of each reaction:
1. **Reaction (a)*:**
- Reactant: An alkene
- Reagent: HBr
- Product: Alkyl bromide with specified stereochemistry, showing a bromine atom (Br) addition.
2. **Reaction (b)‡:**
- Reactant: An alkene
- Reagent: HBr (1.00 equiv.)
- Products: Two different alkyl bromides, illustrating the formation of both possible regioisomers.
3. **Reaction (c)*:**
- Reactant: Phenyl-substituted alkene
- Reagent: HBr
- Product: Alkyl bromide with specified configuration, displaying addition of both bromine (Br) and hydrogen (H) atoms.
4. **Reaction (d):**
- Reactant: Cyclohexene derivative
- Reagent: HCl
- Product: Chloro-cyclohexane derivative.
5. **Reaction (e):**
- Reactant: Cyclohexene derivative
- Reagent: 48% wt. HBr
- Condition: Heat (Δ)
- Product: Alkyl bromide product.
6. **Reaction (f)*:**
- Reactant: Tetramethylcyclobutene
- Reagent: 37% wt. HCl
- Condition: Heat
- Product: Chlorinated cyclobutene with specified stereochemistry.
7. **Reaction (g):**
- Reactant: Diene
- Reagent: [H₂SO₄ / H₂O]
- Product: Methanol adduct with an oxygen-containing functional group (OCH₃).
8. **Reaction (h):**
- Reactant: Substituted alkene with a wedge bond
- Reagent: [H₂SO₄ / Δ] with excess CH₃OH
- Product: Methoxy-alkane derivative reflecting specific stereochemistry.
9. **Reaction (i)*:**
- Reactant: Phenyl-sub
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