(30 Chapter 16: Oxidation of Aromie Compounds 0 Oxidation of Alkyl - CH₂ CH3 2 CH3 CUL 1 Кмпон, H₂O Side chains COOH

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Need details / shows mechanism of how COOH form from CH2CH3 after KMnO4 is added

(30)
Chapter 16: Oxidation of Aromatic
•Compounds
Oxidation
Ет снасна
CH3
CH3
(2
When an
the side chain
-
H
H
уча
of Alkyl Side
CH3
CH3
Bromination of Alkyl benzene
treated
is
alkyl ben zene
at the benzylic position occurs.
H₁Br
Mechanism:
N-Br
O
(Ph CO2)2
benzoyl peroxide
CCL4
KMnO4
H₂O
bromination
KMnO4, NR
H₂O
CH3
Br
Br
chains
CH 3
+
-COOH
Side Chains
with
CH3
HBr
N-bromo succinimide (NBS),
Br H
poth
e
Br 2
+
-CH3
N-H
reaction
Transcribed Image Text:(30) Chapter 16: Oxidation of Aromatic •Compounds Oxidation Ет снасна CH3 CH3 (2 When an the side chain - H H уча of Alkyl Side CH3 CH3 Bromination of Alkyl benzene treated is alkyl ben zene at the benzylic position occurs. H₁Br Mechanism: N-Br O (Ph CO2)2 benzoyl peroxide CCL4 KMnO4 H₂O bromination KMnO4, NR H₂O CH3 Br Br chains CH 3 + -COOH Side Chains with CH3 HBr N-bromo succinimide (NBS), Br H poth e Br 2 + -CH3 N-H reaction
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