3.3 A block of copper of mass 2.00 kg (C,m=24.44 J K-l mol-') and temperature 0°C is introduced into an insulated container in which there is 1.00 mol H,O(g) at 100°C and 1.00 atm. (a) Assuming all the steam is condensed to water, what will be the final temperature of the system, the heat transferred from water to copper, and the entropy change of the water, copper, and the total system? (b) In fact, some water vapour is present at equilibrium. From the vapour pressure of water at the temperature calculated in (a), and assuming that the heat capacities of both gaseous and liquid water are constant and given by their values at that temperature, obtain an improved value of the final temperature, the heat transferred, and the various entropies. (Hint. You will need to make plausible approximations.) · is

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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3.3 A block of copper of mass 2.00 kg (C, m = 24.44 J K-l mol-1) and
temperature 0°C is introduced into an insulated container in which there is
1.00 mol H,O(g) at 100°C and 1.00 atm. (a) Assuming all the steam is
condensed to water, what will be the final temperature of the system, the heat
transferred from water to copper, and the entropy change of the water,
copper, and the total system? (b) In fact, some water vapour is present at
equilibrium. From the vapour pressure of water at the temperature calculated
in (a), and assuming that the heat capacities of both gaseous and liquid water
are constant and given by their values at that temperature, obtain an improved
value of the final temperature, the heat transferred, and the various entropies.
(Hint. You will need to make plausible approximations.)
p,m
Transcribed Image Text:3.3 A block of copper of mass 2.00 kg (C, m = 24.44 J K-l mol-1) and temperature 0°C is introduced into an insulated container in which there is 1.00 mol H,O(g) at 100°C and 1.00 atm. (a) Assuming all the steam is condensed to water, what will be the final temperature of the system, the heat transferred from water to copper, and the entropy change of the water, copper, and the total system? (b) In fact, some water vapour is present at equilibrium. From the vapour pressure of water at the temperature calculated in (a), and assuming that the heat capacities of both gaseous and liquid water are constant and given by their values at that temperature, obtain an improved value of the final temperature, the heat transferred, and the various entropies. (Hint. You will need to make plausible approximations.) p,m
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