Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Nucleophilic Properties in Organic Compounds
**Question: 3. Which of the following are nucleophiles?**
The image presents four different organic compounds labeled 1 through 4. Below is a detailed description of each compound shown:
1. **Compound 1**: This is a hydrocarbon with a double bond (alkene) and a branching methyl group, commonly referred to as isobutene or 2-methylpropene. The structure is:
```
CH3
|
CH2=C-CH3
```
2. **Compound 2**: This is methylamine (CH\(_3\)NH\(_2\)), an amine where a methyl group is bonded to an amino group (-NH2).
3. **Compound 3**: This is methoxide ion (CH\(_3\)O\(^-\)), an oxygen anion with a methyl group attached, carrying a negative charge.
4. **Compound 4**: This is 1-butyne (H3C-C≡C-H), an alkyne containing a triple bond between carbons.
In order to identify which of these compounds act as nucleophiles, it's important to understand what a nucleophile is. A nucleophile is a species that donates an electron pair to form a chemical bond in relation to a reaction. Generally, nucleophiles have lone pairs of electrons or are negatively charged.
### Analysis:
- Compounds 2 and 3 are the nucleophiles since both contain lone pairs of electrons on nitrogen (in the case of methylamine) and oxygen (in the case of methoxide), respectively.
- Compound 1, an alkene, and Compound 4, an alkyne, while they contain pi bonds, are not strong nucleophiles.
Thus, the correct nucleophiles among the given compounds are:
- **Compound 2: CH\(_3\)NH\(_2\) (Methylamine)**
- **Compound 3: CH\(_3\)O\(^-\) (Methoxide ion)**
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