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- 1. The two prominent yellow lines in the spectrum of sodium result from transitions to the ground state from the 3p state with the electron spin-up, and from the 3p state with the electron spin-down. The wavelengths these two lines are 589.0 nm and 589.6 nm. (a) Calculate the energies in eV of the photons corresponding to these wavelengths, and the difference in energy of these photons AE. (b) The energy difference you found in part (a) is due to the spin-orbit effect. An electron in the 3p state of sodium experiences an internal magnetic field B, due to the orbital angular momentum. For a magnetic field B₁, the spin-orbit energy splitting is AE = 2µBB₁, where B is the Bohr magneton. Find the orbital magnetic field By from the energy difference AE you found in part (a).3. What are K,L and M lines you discovered in the Moseley's law experi- ment ? 4. What is the Duane Hunt maximum x-ray frequency of a excitation voltage V = 6kV ? 5. Draw a basic shape of the x-ray absorption spectrum of a generic element, denote the Band a lines along with Duane-Hunt cutoff2. Below are the energies of the first 6 energy levels in Lithium as well as the energies of 6 photons. How many of the photons can be created by an electron that transitions between the any two of the first 6 energy levels in Lithium? En (eV) n 1 2 3 4 5 6 -122.4 -30.6 -13.6 -7.65 -4.896 -3.4 Photon Energies (eV) 108.8 2.754 12.562 27.2 47.29 17.0
- Which of these expressions would yield the wavelength of light in meters emitted when an electron drops from orbit n = 3 to n = 2 in a Bohr hydrogen atom? Given h = 4.14 x 10-15 eVs and c = 3.00 x 108 m/s. a. 1.89/hxc b. hc/1.89 c. 1.89 x h x c d. (1.51 + 3.4)/hc e. hc/3.44. An H-atom is in is state. a. What is the probability that the electron is found in sphere given by r ≤ ao b. What is (r) ? c. calculate ().6.An atomic hydrogen atom is immersed in a magnetic field of 12.44 T. For the 2p to 1s transition more than one line will appear due to the Zeeman effect. What is the smallest wavelength separation of these lines? (in units of picometers (pm)).