3. Use the projection operator method to determine the SALCS required for the formation of M-CI o bonds by the eight ligands in an (MozCls)* ion of symmetry Dah. 2 3 Мо 4 Mo 7 [Mo,Clg]4 ion has the form of square parallelipipid with the Mo-Mo unit along the z axis. The point group is D,h. 5 8 (A) How will the d orbitals split in a (Mo2Cls] ion? (B) Determine whether the following transitions are electric dipole allowed in (Mo»Cls]*¯ ion: 1. A2g Aju 2. E, E.

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Chapter1: Chemical Foundations
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please solve question 3
2. Work out the character table for the group C6. Present it in the conventional format, reducing all
exponentials to their simplest form.
3. Use the projection operator method to determine the SALCS required for the formation of M-Cl o
bonds by the eight ligands in an [Mo:Cls]* ion of symmetry Da.
3
Mo 4
Mo
7
[Mo,Clg]4 ion has the form of square parallelipipid with the
Mo-Mo unit along the z axis. The point group is Dah.
5
8
(A) How will the d orbitals split in a [Mo:ClsJ* ion?
(B) Determine whether the following transitions are electric dipole allowed in [Mo2Cls]* ion:
1. Azg
Aju
2. E,
E,
2.
1.
Transcribed Image Text:2. Work out the character table for the group C6. Present it in the conventional format, reducing all exponentials to their simplest form. 3. Use the projection operator method to determine the SALCS required for the formation of M-Cl o bonds by the eight ligands in an [Mo:Cls]* ion of symmetry Da. 3 Mo 4 Mo 7 [Mo,Clg]4 ion has the form of square parallelipipid with the Mo-Mo unit along the z axis. The point group is Dah. 5 8 (A) How will the d orbitals split in a [Mo:ClsJ* ion? (B) Determine whether the following transitions are electric dipole allowed in [Mo2Cls]* ion: 1. Azg Aju 2. E, E, 2. 1.
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