3. Uh oh, the labels fell off the bottles of chloroaniline (FW 127.57). Again. There are three of them, see the table with pKas below. a. You picked one at random, which happened to be the 4-chloroanaline HCI, added 0.252 grams of it to a 50.0 mL volumetric flask and diluted it to the mark. You then titrated it with 0.1045 M KOH, using a calibrated pH clectrode to monitor the titration. Calculate the pH and volumes at some notable points of the titration curve below. Veq equivalence volume Vb added V (L) Acid pka 2-Chloroaniline HCI 2.65 3-Chloroaniline HCI 3.46 4-Chloroaniline HCI 4.15 PH % Veg % Veq Veq b. What are two ways the titration curves of each acid can be used to distinguish the three acids?

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3. Uh oh, the labels fell off the bottles of chloroaniline (FW 127.57). Again. There are three of them, see the
table with pKas below.
a. You picked one at random, which happened to be the 4-chloroanaline*HCI, added 0.252 grams
of it to a 50.0 mL volumetric flask and diluted it to the mark. You then titrated it with 0.1045 M
KOH, using a calibrated pH electrode to monitor the titration. Calculate the pH and volumes at
some notable points of the titration curve below. Veq = equivalence volume
Vb added
V (L)
Acid
2-Chloroaniline HCI 2.65
pH
pka
3-Chloroaniline*HCI 3.46
% Veg
4-Chloroaniline HCI 4.15
% Veg
Veg
b. What are two ways the titration curves of each acid can be used to distinguish the three acids?
Transcribed Image Text:3. Uh oh, the labels fell off the bottles of chloroaniline (FW 127.57). Again. There are three of them, see the table with pKas below. a. You picked one at random, which happened to be the 4-chloroanaline*HCI, added 0.252 grams of it to a 50.0 mL volumetric flask and diluted it to the mark. You then titrated it with 0.1045 M KOH, using a calibrated pH electrode to monitor the titration. Calculate the pH and volumes at some notable points of the titration curve below. Veq = equivalence volume Vb added V (L) Acid 2-Chloroaniline HCI 2.65 pH pka 3-Chloroaniline*HCI 3.46 % Veg 4-Chloroaniline HCI 4.15 % Veg Veg b. What are two ways the titration curves of each acid can be used to distinguish the three acids?
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