3. Please write out the products or reagents (Note:stereochemistry)H3CBr2H3CBr2/H2O(2) "aH3C(1)H3CBr2( Note: anti-stereochemistry)(3)BrCIHH3CC=CHHH2(5)(Note: syn-stereochemistry )Pd/CCH3

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Answered: 3. Please write out the products or…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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3.2 Reaction of (1R,2S)-1-bromo-1,2-dimethylcyclohexane with methanol gives a mixture of products. Provide a stepwise mechanism indicating stereochemically how a mixture is formed. ||CH 3 Br CH3OH CH3 ......CH3 OCH 3 CH3 + OCH3 CH3 CH3
What are the number of stereogenic centers in each and what are the maximum number of stereoisomers in each case? Explain please.
A3.
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3. (i) Classify the following carbocations (methyl, primary, secondary, tertiary, benzylic, allyl, or vinyl). (ii) Which of the following carbocations is more stable? (iii) What kind of rearrangement (methyl shift, alkyl shift, hydride shift, anion shift, other) can be used to interconvert these carbocations? + +
1. Beginning with the single enantiomer of the starting materials listed, draw the product(s) of each reaction, clearly indicating stereochemistry. Indicate major and minor products, where relevant. DNR (does not react) is a possibility. For the cyclohexane, be sure to draw all relevant chair configurations. Br MeOH mod. heat NaOMe MeOH mod. heat Br (continued on back) NaOMe Br MeOH mod. heat NaOMe Subst A-value methyl 1.7 kcal/mol O-Me 0.6 kcal/mol
Identify the nature of following pairs of structures. Write not isomers (samecompound), not isomers (different compounds), constitutional isomers, orcis-trans isomers.
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Indicate whether the pairs of molecules shown below are constitutional isomers, enantiomers, diastereomers, or the same. Please ignore my writing! These are my preliminary thoughts, and this question left me stumped.
5. Consider the reaction below: ÇI CH3 CH CHCH3 CH, CHCHCH, + ci CH3 (a) State the type of bond cleavage involved. (b) Compare the stability of the product to (CH3)2CHCH;CH2 and explain.
Predict the organic products of the following reaction. Show stereochemistry clearly. The (R) or (S) designation for each stereocenter carbon atom is specified adjacent to the answer box, please draw the products accordingly (1S,2R) 1) OsO4, pyridine H 2) Na2SO3 or NaHSO3 in H20 (1R,2S)

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3. Please write out the products or reagents (Note: stereochemistry ) H3C Br2 H3C Br/H20 (2) (1) H3C H3C Br2 ( Note: anti-stereochemistry) (3) BrCI H H,C C=C H H H2 (5) (Note: syn-stereochemistry) Pd/C CH3