3. Methanol is finding increased acceptance as an alternative fuel. The combustion is given by the following unbalanced reaction: CH3OH (1) + O2 (g) → CO2 (g) + H2O (g) a) What is the change of enthalpy for the reaction if AH CH3OH (1) = -238.6 kJ/mol AH CO2 (g) =-393.5 kJ/mol AH H2O (g) = -241.8 kJ/mol

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Question 5: parts a, b, and c.

**Transcription for Educational Website**

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**5. Methanol as an Alternative Fuel**

Methanol is gaining acceptance as an alternative fuel. The following unbalanced chemical reaction represents its combustion:

\[ \text{CH}_3\text{OH (l)} + \text{O}_2\text{ (g)} \rightarrow \text{CO}_2\text{ (g)} + \text{H}_2\text{O (g)} \]

**a) Enthalpy Change Calculation:**

To determine the change in enthalpy (\( \Delta H \)) for the reaction, the following standard enthalpy values (kJ/mol) are considered:

- \( \Delta H_f^\circ \text{CH}_3\text{OH (l)} = -238.6 \, \text{kJ/mol} \)
- \( \Delta H_f^\circ \text{CO}_2\text{ (g)} = -393.5 \, \text{kJ/mol} \)
- \( \Delta H_f^\circ \text{H}_2\text{O (g)} = -241.8 \, \text{kJ/mol} \)

**b) Enthalpy Change for 252 ml of Methanol:**

Calculate the enthalpy change when 252 ml of methanol (density = 0.924 g/ml) is combusted completely.

**c) Enthalpy Diagram Construction:**

Below is a typical enthalpy diagram for the reaction:

- **Diagram Description:**
  - **Axes:** The vertical axis represents enthalpy (\( \Delta H \)), while the horizontal axis represents time.
  - **Curve:** The curve starts at point R (reactants) with higher enthalpy, drops to point P (products) with lower enthalpy, indicating an exothermic reaction.

The diagram illustrates the decrease in enthalpy over time during the combustion of methanol.

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This transcription provides clarity on methanol combustion, enthalpy changes, and offers an illustrative graph to aid in understanding the reaction dynamics.
Transcribed Image Text:**Transcription for Educational Website** --- **5. Methanol as an Alternative Fuel** Methanol is gaining acceptance as an alternative fuel. The following unbalanced chemical reaction represents its combustion: \[ \text{CH}_3\text{OH (l)} + \text{O}_2\text{ (g)} \rightarrow \text{CO}_2\text{ (g)} + \text{H}_2\text{O (g)} \] **a) Enthalpy Change Calculation:** To determine the change in enthalpy (\( \Delta H \)) for the reaction, the following standard enthalpy values (kJ/mol) are considered: - \( \Delta H_f^\circ \text{CH}_3\text{OH (l)} = -238.6 \, \text{kJ/mol} \) - \( \Delta H_f^\circ \text{CO}_2\text{ (g)} = -393.5 \, \text{kJ/mol} \) - \( \Delta H_f^\circ \text{H}_2\text{O (g)} = -241.8 \, \text{kJ/mol} \) **b) Enthalpy Change for 252 ml of Methanol:** Calculate the enthalpy change when 252 ml of methanol (density = 0.924 g/ml) is combusted completely. **c) Enthalpy Diagram Construction:** Below is a typical enthalpy diagram for the reaction: - **Diagram Description:** - **Axes:** The vertical axis represents enthalpy (\( \Delta H \)), while the horizontal axis represents time. - **Curve:** The curve starts at point R (reactants) with higher enthalpy, drops to point P (products) with lower enthalpy, indicating an exothermic reaction. The diagram illustrates the decrease in enthalpy over time during the combustion of methanol. --- This transcription provides clarity on methanol combustion, enthalpy changes, and offers an illustrative graph to aid in understanding the reaction dynamics.
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