3. (II) Sketch a PV diagram of the following process: 2.5 L of ideal gas at atmospheric pressure is cooled at constant pressure to a volume of 1.0 L, and then expanded isother- mally back to 2.5 L, whereupon the pressure is increased at constant volume until the original pressure is reached.
3. (II) Sketch a PV diagram of the following process: 2.5 L of ideal gas at atmospheric pressure is cooled at constant pressure to a volume of 1.0 L, and then expanded isother- mally back to 2.5 L, whereupon the pressure is increased at constant volume until the original pressure is reached.
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
Transcribed Image Text:**Problem 3: PV Diagram Sketch**
Sketch a \( PV \) diagram of the following process: 2.5 L of ideal gas at atmospheric pressure is cooled at constant pressure to a volume of 1.0 L, and then expanded isothermally back to 2.5 L, whereupon the pressure is increased at constant volume until the original pressure is reached.
### Detailed Explanation:
1. **Starting Condition:**
- Initial Volume (\( V_i \)): 2.5 L
- Initial Pressure (\( P_i \)): Atmospheric pressure
2. **Cooling at Constant Pressure:**
- The gas is cooled at constant pressure.
- The volume decreases from 2.5 L to 1.0 L.
- On the \( PV \) diagram, this is represented as a horizontal line from (2.5 L, \( P_i \)) to (1.0 L, \( P_i \)).
3. **Isothermal Expansion:**
- The gas is then expanded isothermally, meaning at constant temperature.
- The volume increases back to 2.5 L.
- Since it's isothermal, the pressure decreases as the volume increases according to Boyle's Law (\( PV = \text{constant} \)).
- On the \( PV \) diagram, this appears as a curved line from (1.0 L, \( P_i \)) to (2.5 L, lower pressure).
4. **Increasing Pressure at Constant Volume:**
- Finally, the pressure is increased back to the original pressure at constant volume.
- The volume remains at 2.5 L while the pressure increases back to \( P_i \).
- On the \( PV \) diagram, this is represented as a vertical line from (2.5 L, lower pressure) to (2.5 L, \( P_i \)).
### Graphical Representation:
A PV diagram generally plots Pressure (P) on the y-axis and Volume (V) on the x-axis.
- The horizontal line represents the constant pressure cooling process.
- The isothermal process appears as a curve, reflecting the inverse relationship between pressure and volume.
- The vertical line indicates the process of increasing pressure at constant volume.
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