3. For the complex [N(Et)-][V(CO)«] (where Et = C2H3) a) Give the name of the complex, and what is the oxidation state of the metal? b) Show the molecular orbital energy level diagram for the complex considering o and r interaction of the orbitals (Symmetry Adapted Orbitals for On: s=a1g, Px=tiu, Pytiu, Pz-tiu, d²=eg, d=eg, dxy=t2g, du=t2g, dyzt25). c) Are all metal-ligand bonds in [V(CO)«]° and [V(CO)6] vanadium complexes equal? Explain the structures in detail and compare them.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 94CWP: Which of the following statement(s) is( are) true? a. The coordination number of a metal ion in an...
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3. For the complex [N(Et)4][V(CO)6] (where Et = C2H5)
a) Give the name of the complex, and what is the oxidation state of the metal?
b) Show the molecular orbital energy level diagram for the complex considering o and n
interaction of the orbitals (Symmetry Adapted Orbitals for On: s=a1g, Px=tiu, Py=tlu, Pz=tlu,
dz?=eg, d=eg, dxy=t2g, dx=t2g, dyz-t2g ).
c) Are all metal-ligand bonds in [V(CO)6] and [V(CO)6] vanadium complexes equal?
Explain the structures in detail and compare them.
Transcribed Image Text:3. For the complex [N(Et)4][V(CO)6] (where Et = C2H5) a) Give the name of the complex, and what is the oxidation state of the metal? b) Show the molecular orbital energy level diagram for the complex considering o and n interaction of the orbitals (Symmetry Adapted Orbitals for On: s=a1g, Px=tiu, Py=tlu, Pz=tlu, dz?=eg, d=eg, dxy=t2g, dx=t2g, dyz-t2g ). c) Are all metal-ligand bonds in [V(CO)6] and [V(CO)6] vanadium complexes equal? Explain the structures in detail and compare them.
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