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E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)2] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?

E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)2] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
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Answer last 3 parts E to G

1. Consider the coordination compound Na4[Fe(ONO)2(Ox)2]. A. Write the systematic name of the compound. B. Indicate the (i) oxidation state, (ii) coordination number, and (iii) type of hybridization of the central metal in the complex anion. C. Considering the geometry of the complex anion and the ligand field strength, show how the five d orbitals split and how the d electrons are distributed in these orbitals. Label each d orbital (e.g. dxy). D. Is the complex anion paramagnetic? Justify your answer. E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)₂] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?
Transcribed Image Text:1. Consider the coordination compound Na4[Fe(ONO)2(Ox)2]. A. Write the systematic name of the compound. B. Indicate the (i) oxidation state, (ii) coordination number, and (iii) type of hybridization of the central metal in the complex anion. C. Considering the geometry of the complex anion and the ligand field strength, show how the five d orbitals split and how the d electrons are distributed in these orbitals. Label each d orbital (e.g. dxy). D. Is the complex anion paramagnetic? Justify your answer. E. Linkage isomerism is possible for the complex anion. Write the chemical formula of the three possible linkage isomers. F. The complex anion has two geometric isomers, cis and trans. One of these two exhibits optical isomerism. Draw the structures of the enantiomeric pair. G. Malonate (C3H₂04) is a ligand that is similar to oxalate (C₂04). Both are dicarboxylate anions that are capable of bidentate mode of binding through two oxygen atoms. If the oxalate ligands in Na4[Fe(ONO)2(ox)₂] are replaced with malonate ligands, what is the systematic name of the resulting coordination compound?
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