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- (a) Explain how pyrrole is isoelectronic with the cyclopentadienyl anion.(b) Specifically, what is the difference between the cyclopentadienyl anion and pyrrole?(c) Draw resonance forms to show the charge distribution on the pyrrole structure.The longest wavelength electronic transition in simple unsaturated hydrocarbons corresponds to a transition from the highest occupied molecular orbita l (HOMO) to the lowest unoccupied molecular orbita l (LUMO) . Predict the energy of the HOMO to LUMO separation in (a) ethane. (b) butadiene. and (c) benzene.Answer Q43, 44, 45
- (C) Provide the starting materials (diene and dienophile) necessary to form the ind product through a Diels-Alder reaction (beware of the stereochemical information). (a) (b) (c) (d) - Diene - Dienophile- Diene Dienophile - Diene + Dienophile- -Diene Dienophile- A Dor Br Br A ✓ CO₂Me CO₂Me A 4 A MeO CN4) Identify the reagents to prepare the following compound via Diels-Alder reaction Coalf DI Caotl a) X + .wolt •Looft b) x + you to c) of + Xco coot الاك d) None2) Predict the major product for each Diels-Alder reaction. Include stereochemistry where appropriate. H. C=N (a) H H. CH3 CH;O, (b) Ph (c) Ph
- [References) The degree of unsaturation, or index of hydrogen deficiency, is the number of pi bonds plus rings in a molecule. Specify the degree of unsaturation (index of hydrogen deficiency) of the following formulas: (a) C4H4 (b) C13H1402 (c) C6H10N₂04 Submit Answer Retry Entire Group 9 more group attempts remainingDraw the structures of the two linkage isomers; include representations of the resonance forms of the NO2- Explain the origin of and the differences in the position of both absorption maxima in the UV-visible spectra of the two isomers. Studies have shown the isomerization to be an intramolecular process. Comment on a possible mechanism. Draw a possible transition state for the isomerization process.Enthalpy (H) (B) (A) (C) (D) Reaction Progress Considering the energy profile and the reaction mechanism given above, circle which of the following alkyl halides is a candidate molecule to follow this mechanism: CI CI .CI CI (A) (B) (C) (D) Give the name and the type of the mechanism for this reaction, and hence, (showing clearly the electron-flow) represent the reaction mechanism.
- Furan undergoes electrophilic aromatic substitution more readily than benzene; mild reagents and conditions are sufficient.For example, furan reacts with bromine to give 2-bromofuran.(a) Propose mechanisms for the bromination of furan at the 2-position and at the 3-position. Draw the resonance forms ofeach sigma complex, and compare their stabilities.(b) Explain why furan undergoes bromination (and other electrophilic aromatic substitutions) primarily at the 2-position.O Br O123furan 2-bromofuraneaching and le y! Yahoo now.com O Papa's Bakeria - Pla. [Review Topics] [References] The degree of unsaturation, or index of hydrogen deficiency, is the number of pi bonds plus rings in a molecule. Specify the degree of unsaturation (index of hydrogen deficiency) of the following formulas: (a) C24H30 (b) CGH1003 (c) C,H,N2 Retry Entire Group 7 more group attempts remaining Submit Answer Mail hp %2: 近6) Provide the enantiomeric Diels-Alder adducts that would form from the following reaction along with the two transition states leading to them: + HO₂C