3. Consider the reaction Br2 (g) + Cl2 (9) 2 BrCl (g) Kp = 1.11 x 10 at 150 K. A reaction mixture initially contains a Br₂ partial pressure of 0.993 atm and a Cl₂ partial pressure of 0.967 atm at 150 K. Calculate the equilibrium partial pressure of each reactant and product. 4. Consider the reaction CO (g) + H₂O (g) CO₂ (g) + H₂ (g) A reaction mixture initially contains a CO partial pressure of 1.768 atm and a H₂O partial pressure of 2.324 atm at 2000 K. Calculate the equilibrium partial pressures of each reactant and product. p= 0.0611 at 2000K.
3. Consider the reaction Br2 (g) + Cl2 (9) 2 BrCl (g) Kp = 1.11 x 10 at 150 K. A reaction mixture initially contains a Br₂ partial pressure of 0.993 atm and a Cl₂ partial pressure of 0.967 atm at 150 K. Calculate the equilibrium partial pressure of each reactant and product. 4. Consider the reaction CO (g) + H₂O (g) CO₂ (g) + H₂ (g) A reaction mixture initially contains a CO partial pressure of 1.768 atm and a H₂O partial pressure of 2.324 atm at 2000 K. Calculate the equilibrium partial pressures of each reactant and product. p= 0.0611 at 2000K.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Chemical Equilibrium Problems
#### 3. Reaction Analysis
**Reaction:**
\[ \text{Br}_2(g) + \text{Cl}_2(g) \rightleftharpoons 2 \text{BrCl}(g) \]
**Equilibrium Constant (K\_p):**
\[ K\_p = 1.11 \times 10^{-4} \, \text{at 150 K} \]
**Initial Conditions:**
- Partial pressure of Br\(_2\) = 0.993 atm
- Partial pressure of Cl\(_2\) = 0.967 atm
**Task:**
Calculate the equilibrium partial pressures of Br\(_2\), Cl\(_2\), and BrCl at 150 K.
#### 4. Reaction Analysis
**Reaction:**
\[ \text{CO}(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{CO}_2(g) + \text{H}_2(g) \]
**Equilibrium Constant (K\_p):**
\[ K\_p = 0.0611 \, \text{at 2000 K} \]
**Initial Conditions:**
- Partial pressure of CO = 1.768 atm
- Partial pressure of H\(_2\)O = 2.324 atm
**Task:**
Calculate the equilibrium partial pressures of CO, H\(_2\)O, CO\(_2\), and H\(_2\) at 2000 K.
---
**Instructions for Solving the Problems:**
1. **Write the expression for K\_p:** Based on the reaction equations, write the expression for K\_p using the ratio of products to reactants, each raised to the power of their coefficients in the balanced equation.
2. **Use an ICE Table:** Set up an ICE (Initial, Change, Equilibrium) table to help visualize changes in partial pressures from initial conditions to equilibrium.
3. **Solve for Changes (x):** Use algebraic methods to solve for changes in pressure (\(x\)) and determine the equilibrium pressures.
4. **Calculate Equilibrium Pressures:** Use \(x\) to find the equilibrium pressures for each substance.
5. **Verify Results:** Ensure your calculated pressures satisfy the K\_p expression.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd6cc73a6-72c8-4e2b-a22b-5b06a5805dfc%2Ff2bf4936-6aba-4c0a-9a18-c61480ee9138%2Fb4y51ai_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Chemical Equilibrium Problems
#### 3. Reaction Analysis
**Reaction:**
\[ \text{Br}_2(g) + \text{Cl}_2(g) \rightleftharpoons 2 \text{BrCl}(g) \]
**Equilibrium Constant (K\_p):**
\[ K\_p = 1.11 \times 10^{-4} \, \text{at 150 K} \]
**Initial Conditions:**
- Partial pressure of Br\(_2\) = 0.993 atm
- Partial pressure of Cl\(_2\) = 0.967 atm
**Task:**
Calculate the equilibrium partial pressures of Br\(_2\), Cl\(_2\), and BrCl at 150 K.
#### 4. Reaction Analysis
**Reaction:**
\[ \text{CO}(g) + \text{H}_2\text{O}(g) \rightleftharpoons \text{CO}_2(g) + \text{H}_2(g) \]
**Equilibrium Constant (K\_p):**
\[ K\_p = 0.0611 \, \text{at 2000 K} \]
**Initial Conditions:**
- Partial pressure of CO = 1.768 atm
- Partial pressure of H\(_2\)O = 2.324 atm
**Task:**
Calculate the equilibrium partial pressures of CO, H\(_2\)O, CO\(_2\), and H\(_2\) at 2000 K.
---
**Instructions for Solving the Problems:**
1. **Write the expression for K\_p:** Based on the reaction equations, write the expression for K\_p using the ratio of products to reactants, each raised to the power of their coefficients in the balanced equation.
2. **Use an ICE Table:** Set up an ICE (Initial, Change, Equilibrium) table to help visualize changes in partial pressures from initial conditions to equilibrium.
3. **Solve for Changes (x):** Use algebraic methods to solve for changes in pressure (\(x\)) and determine the equilibrium pressures.
4. **Calculate Equilibrium Pressures:** Use \(x\) to find the equilibrium pressures for each substance.
5. **Verify Results:** Ensure your calculated pressures satisfy the K\_p expression.
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