1. One process to make molecular hydrogen gas passes hot steam over graphite to create a mixture of carbon monoxide and hydrogen. C(s, graphite) + H20(g) = CO(g) + H2(g) K, = 28.3 What will be the equilibrium partial pressures of H,O(g) and H;lg) if the reaction mixture initially only contains water vapor at a pressure of 7.65 atm and an excess of graphite? 2. Ammonia reacts with water to produce ammonium ion and hydroxide ion as shown in the equation below. NH3(aq) + H20(1) = NH; (aq) + OH¯(aq) Ke = 1.79 x 10-5 If the reaction mixture initially only contains 0.255 M NH, and water, what will be the equilibrium concentrations of NH;(aq) and NH, (aq)?

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**Chemical Equilibrium Problems**

1. **Hydrogen Production via Graphite Reaction**

   One process to make molecular hydrogen gas involves passing hot steam over graphite to create a mixture of carbon monoxide and hydrogen. The chemical reaction is represented by:

   \[
   C(s, \text{graphite}) + H_2O(g) \rightleftharpoons CO(g) + H_2(g)
   \]

   The equilibrium constant (\(K_p\)) for this reaction is 28.3.

   *Problem:*  
   What will be the equilibrium partial pressures of \(H_2O(g)\) and \(H_2(g)\) if the reaction mixture initially only contains water vapor at a pressure of 7.65 atm and an excess of graphite?

2. **Ammonia Reaction with Water**

   Ammonia reacts with water to produce ammonium ion and hydroxide ion as shown in the equation below:

   \[
   NH_3(aq) + H_2O(l) \rightleftharpoons NH_4^+(aq) + OH^-(aq) \quad K_c = 1.79 \times 10^{-5}
   \]

   *Problem:*  
   If the reaction mixture initially only contains 0.255 M \(NH_3\) and water, what will be the equilibrium concentrations of \(NH_3(aq)\) and \(NH_4^+(aq)\)?

**Note:** There are no graphs or diagrams associated with this text. The problems focus on calculating equilibrium positions for specified chemical reactions.
Transcribed Image Text:**Chemical Equilibrium Problems** 1. **Hydrogen Production via Graphite Reaction** One process to make molecular hydrogen gas involves passing hot steam over graphite to create a mixture of carbon monoxide and hydrogen. The chemical reaction is represented by: \[ C(s, \text{graphite}) + H_2O(g) \rightleftharpoons CO(g) + H_2(g) \] The equilibrium constant (\(K_p\)) for this reaction is 28.3. *Problem:* What will be the equilibrium partial pressures of \(H_2O(g)\) and \(H_2(g)\) if the reaction mixture initially only contains water vapor at a pressure of 7.65 atm and an excess of graphite? 2. **Ammonia Reaction with Water** Ammonia reacts with water to produce ammonium ion and hydroxide ion as shown in the equation below: \[ NH_3(aq) + H_2O(l) \rightleftharpoons NH_4^+(aq) + OH^-(aq) \quad K_c = 1.79 \times 10^{-5} \] *Problem:* If the reaction mixture initially only contains 0.255 M \(NH_3\) and water, what will be the equilibrium concentrations of \(NH_3(aq)\) and \(NH_4^+(aq)\)? **Note:** There are no graphs or diagrams associated with this text. The problems focus on calculating equilibrium positions for specified chemical reactions.
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