3. Complete the following table based on the 'H NMR spectrum of unknown compound G whose molecular formula is C,H140. 2x2+2=14=7I # of 8 (ppm) Integration Multiplicity Partial structure neighboring H
3. Complete the following table based on the 'H NMR spectrum of unknown compound G whose molecular formula is C,H140. 2x2+2=14=7I # of 8 (ppm) Integration Multiplicity Partial structure neighboring H
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### 'H NMR Spectrum Analysis
The table below analyzes the ^1H NMR spectrum of an unknown compound G, with a molecular formula of C<sub>7</sub>H<sub>14</sub>O. The data presents chemical shifts, integration, multiplicity, and the number of neighboring hydrogen atoms, which help identify the partial structure.
| δ (ppm) | Integration | Multiplicity | # of Neighboring H | Partial Structure |
|---------|-------------|--------------|--------------------|-------------------|
| 2.08 | 2 | Doublet | 1 | |
| 9.58 | 9 | Singlet | 0 | |
| 3.00 | 3 | Triplet | 2 | |
### ^13C NMR Spectrum Analysis
The table below should be completed using the ^13C NMR spectrum for the same unknown compound G. Each signal is assigned to a partial structure.
| Partial Structure | Partial Structure |
|-------------------|-------------------|
| a | d |
| b | e |
### Structural Assignment
- **Hydrogen Assignments:** Assign the hydrogen signals (A-C) to the appropriate protons in the molecule.
- **Carbon Assignments:** Assign the carbon signals (a-e) to the corresponding carbon atoms in the molecule's structure.
### NMR Spectra Explanation
#### ^1H NMR Spectrum for C<sub>7</sub>H<sub>14</sub>O:
- The spectrum shows three distinct peaks:
- **Peak A**: At 2.08 ppm, with an integration of 2 generating a doublet, indicating a hydrogen atom next to one other hydrogen.
- **Peak B**: At 9.58 ppm, with an integration of 9 and a singlet, suggesting the presence of a isolated hydrogen environment without neighboring hydrogens.
- **Peak C**: At 3.00 ppm, with an integration of 3 producing a triplet, indicative of hydrogen atoms adjacent to two other hydrogens.
#### ^13C NMR Spectrum for C<sub>7</sub>H<sub>14</sub>O:
- The spectrum includes several peaks labeled a to e:
- **Peak a** begins near 220 ppm.
- Additional peaks labeled b, c,
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