3. Classify the reactions below as oxidation reduction reactions: (3 pts) OH (1) (II) Br (III) 4. What is the mostly likely product outcome of the following reaction? (3 pts) 1. КMпОд, ОН", Cold 2. Hао НОС HỌC HO I II III HO HO IV
3. Classify the reactions below as oxidation reduction reactions: (3 pts) OH (1) (II) Br (III) 4. What is the mostly likely product outcome of the following reaction? (3 pts) 1. КMпОд, ОН", Cold 2. Hао НОС HỌC HO I II III HO HO IV
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Oxidation-Reduction Reactions and Reaction Products
#### 3. Classify the reactions below as oxidation-reduction reactions: (3 pts)
**Reaction I:**
- **Reactants:** A ketone (butan-2-one) is shown.
- **Product:** The corresponding alcohol (butane-2-ol) is produced.
- **Explanation:** This is a reduction reaction, where the ketone is reduced to an alcohol.
**Reaction II:**
- **Reactants:** A benzene ring with an acetyl side chain (phenylacetone).
- **Product:** The ketone is reduced to a hydrocarbon chain with a cyclohexane ring.
- **Explanation:** This reaction involves reduction, indicated by the formation of a fully saturated cyclohexane from a benzene ring.
**Reaction III:**
- **Reactants:** A benzene ring with an ethyl side chain.
- **Product:** The ethyl side chain is converted to bromoethyl (an alkyl bromide).
- **Explanation:** This reaction represents a substitution, not oxidation-reduction.
#### 4. What is the most likely product outcome of the following reaction? (3 pts)
**Reaction Conditions:**
- **Reagents Used:**
- Step 1: KMnO₄, OH⁻, Cold
- Step 2: H₂O
**Reactants:**
- A cyclopentene structure with a substituent.
**Possible Products:**
- **I:** Cyclopentane with an alcoholic side chain.
- **II:** Cyclopentanone.
- **III:** Cyclopentane with two ketone groups.
- **IV:** Cyclopentane with two hydroxyl groups.
- **V:** Lactone, a cyclic ester derived from pentanoic acid.
**Explanation:**
The most likely product under these conditions is a diol from the syn-dihydroxylation of the alkene, which is product **IV.** This reaction involves hydroxylation using cold, dilute potassium permanganate.
### Summary:
This exercise identifies reaction types and predicts chemical outcomes, enhancing understanding of organic reaction mechanisms, particularly oxidation-reduction dynamics and specific reagent effects like dihydroxylation with KMnO₄.
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