3. A steel plate of area 100 cm² steel is undergoing a corrosion process resulting in a weight change of 2.89 x 10-5 gm/s. The equivalent current density associated with this process is a. 10 mA/cm² b. 1 mA/cm² c. 100 mA/cm² d. 0.10 mA/cm²

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Chapter1: Chemical Foundations
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Solve 3 please
q=ce where q is the charge density and E is the electrochemical potential. In
cyclic voltammetry, the effect of increasing the potential sweep rate, dE/dt (t is time) is to
a. increase the current density.
b. increase the rate of the corresponding oxidation/reduction
c. increase the charge transfer resistance.
d. all of the above.
process.
3. A steel plate of area 100 cm² steel is undergoing a corrosion process resulting in a weight
change of 2.89 x 10-5 gm/s. The equivalent current density associated with this process is
a. 10 mA/cm² b. 1 mA/cm² c. 100 mA/cm²
d. 0.10 mA/cm²
4. The thermodynamics of a passivation process can be examined using
a. mixed potential theory or Evan's diagrams.
b. Potential-pH or Pourbaix diagrams.
c. linear sweep voltammetry.
d. the electrochemical series of reduction potentials.
5. Consider the electrochemical cell: Cu/10-4 M Cu²+, 1M H*/Pt/H₂ (a=1). Determine the
equilibrium potential versus the indicated reference electrode.
a. 0.342 V. b. 0.082 V. c. 0.222 V. 0.462 V.
Transcribed Image Text:q=ce where q is the charge density and E is the electrochemical potential. In cyclic voltammetry, the effect of increasing the potential sweep rate, dE/dt (t is time) is to a. increase the current density. b. increase the rate of the corresponding oxidation/reduction c. increase the charge transfer resistance. d. all of the above. process. 3. A steel plate of area 100 cm² steel is undergoing a corrosion process resulting in a weight change of 2.89 x 10-5 gm/s. The equivalent current density associated with this process is a. 10 mA/cm² b. 1 mA/cm² c. 100 mA/cm² d. 0.10 mA/cm² 4. The thermodynamics of a passivation process can be examined using a. mixed potential theory or Evan's diagrams. b. Potential-pH or Pourbaix diagrams. c. linear sweep voltammetry. d. the electrochemical series of reduction potentials. 5. Consider the electrochemical cell: Cu/10-4 M Cu²+, 1M H*/Pt/H₂ (a=1). Determine the equilibrium potential versus the indicated reference electrode. a. 0.342 V. b. 0.082 V. c. 0.222 V. 0.462 V.
Expert Solution
Step 1: step 1 of 2

To calculate the equivalent current density associated with this process, we can use the following equation:

Currentdensity(mA/cm²)=(Weightchange(g/s))/(Molarmass(g/mol)Numberofelectronstransferred(mol/electron)Faradayconstant(C/molelectron))

Given:

  • Weight change (g/s) = 2.89 x 10⁻⁵ gm/s
  • Molar mass of iron (g/mol) = 55.845
  • Number of electrons transferred per iron atom (mol/electron) = 2
  • Faraday constant (C/mol * electron) = 96,485


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