3. A solution contains only these ions: silver, tin (IV), iron (III), and potassium. Prepare a flow chart to show how you would separate and identify the four ions in this solution.
3. A solution contains only these ions: silver, tin (IV), iron (III), and potassium. Prepare a flow chart to show how you would separate and identify the four ions in this solution.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Problem Statement:**
3. A solution contains only these ions: silver, tin (IV), iron (III), and potassium. Prepare a flow chart to show how you would separate and identify the four ions in this solution.
**Flow Chart Explanation:**
To create a flow chart for separating and identifying the ions, you should follow these steps:
1. **Silver Ion (Ag⁺) Separation:**
- Add hydrochloric acid (HCl) to the solution.
- Silver ions will form a white precipitate of silver chloride (AgCl).
- Filter and confirm Ag⁺ presence by ammonia test (AgCl dissolves in NH₃).
2. **Tin (IV) Ion (Sn⁴⁺) Separation:**
- After removing Ag⁺, add hydrogen sulfide (H₂S) in acidic condition.
- Tin ions will precipitate as tin sulfide (SnS₂), a yellow precipitate.
- Confirm by dissolving in concentrated HCl.
3. **Iron (III) Ion (Fe³⁺) Separation:**
- Use the remaining solution after Ag⁺ and Sn⁴⁺ removal.
- Add sodium hydroxide (NaOH) to precipitate iron (III) hydroxide (Fe(OH)₃), a brown precipitate.
- Confirm presence by test with potassium thiocyanate (KSCN) to form a red complex.
4. **Potassium Ion (K⁺) Identification:**
- Since K⁺ does not form precipitates easily, use the flame test.
- Potassium ions will produce a lilac-colored flame when introduced to a flame source.
By following this procedure, you will effectively separate and identify silver, tin (IV), iron (III), and potassium ions from the solution.
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