3) Buffer C: 100.0 mL at pH = 12.000, [conj. base]: = 0.500 M %3D a) What conjugate pair should be chosen? Conjugate acid: Conjugate base: b) Calculate the molarity of the conjugate acid necessary to obtain the desired pH using the Henderson-Hasselbalch equation. Show the variable equation with specific species and Ka values.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Part A B and C

**Buffer C: Preparation and Analysis**

- **Volume and Concentration:**
  - Volume: 100.0 mL
  - pH: 12.000
  - Concentration of conjugate base: 0.500 M

- **Tasks:**

  **a) Selection of Conjugate Pair:**
  - Determine the appropriate conjugate acid and conjugate base pair for Buffer C.
    - **Conjugate acid:** _______________
    - **Conjugate base:** _______________

  **b) Calculation of Conjugate Acid Molarity:**
  - Utilize the Henderson-Hasselbalch equation to calculate the molarity of the conjugate acid needed for the desired pH.
  - Provide the variable equation including specific chemical species and their \( K_a \) values.
    - **Answer:** _______________

  **c) Source and Mass of Conjugate Acid:**
  - If the conjugate acid is derived from a solid, compute the mass (in grams) of the solid required.
  - Include the identification of the solid in your response.

This comprehensive analysis ensures an accurate preparation and understanding of Buffer C's chemical properties and necessary components.
Transcribed Image Text:**Buffer C: Preparation and Analysis** - **Volume and Concentration:** - Volume: 100.0 mL - pH: 12.000 - Concentration of conjugate base: 0.500 M - **Tasks:** **a) Selection of Conjugate Pair:** - Determine the appropriate conjugate acid and conjugate base pair for Buffer C. - **Conjugate acid:** _______________ - **Conjugate base:** _______________ **b) Calculation of Conjugate Acid Molarity:** - Utilize the Henderson-Hasselbalch equation to calculate the molarity of the conjugate acid needed for the desired pH. - Provide the variable equation including specific chemical species and their \( K_a \) values. - **Answer:** _______________ **c) Source and Mass of Conjugate Acid:** - If the conjugate acid is derived from a solid, compute the mass (in grams) of the solid required. - Include the identification of the solid in your response. This comprehensive analysis ensures an accurate preparation and understanding of Buffer C's chemical properties and necessary components.
Expert Solution
Step 1

We need to an acid whose pKa is close to 12. then we make a solution of the acid and its conjugate base.

The acid pKa colse to 12 are H3PO4 and ascorbic acid (H2C2H6O2)

pKa3 of H3PO4 = 12.32

pKa2 of H2C2H6O2 = 11.79

 

The solution of Na2HPO4 and NaOH can be used make buffer solution:

let the Buffer solution Na3PO4(PO4-3) and Na2HPO4(HPO4-2).

molar mass of Na3PO4 = 163.94 g/mol

molar mass of Na2HPO4 = 141.96 g/mol

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