2Fe3+(aq) + Mn(s)  2Fe2+(aq) + Mn2+(aq) The anode reaction is:     +              +     The cathode reaction is:     +              +     In the external circuit, electrons migrate     the Fe2+|Fe3+ electrode     the Mn|Mn2+ electrode. In the salt bridge, anions migrate     the Fe2+|Fe3+ compartment     the Mn|Mn2+ compartment.

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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A voltaic cell is constructed in which the following cell reaction occurs. The half-cell compartments are connected by a salt bridge.

2Fe3+(aq) + Mn(s)  2Fe2+(aq) + Mn2+(aq)

The anode reaction is:

    +              +    



The cathode reaction is:

    +              +    



In the external circuit, electrons migrate 

 

 the Fe2+|Fe3+ electrode 

 

 the Mn|Mn2+ electrode.

In the salt bridge, anions migrate 

 

 the Fe2+|Fe3+ compartment 

 

 the Mn|Mn2+ compartment.

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