27. Answer ALL parts of this question. (a) (b) (c) The secondary alcohol shown below can be synthesised by reacting benzaldehyde (C6HSCHO) with methyl magnesium bromide (CH3MgBr), followed by the addition of aqueous acid (H*/H₂O). H -C-CH3 I он Outline, using curly arrows, the mechanism of this reaction. Suggest, without giving details of mechanism, an alternative pair of starting materials (one is a carbonyl compound and the other is a Grignard reagent) that could also be used to synthesise this compound. The naturally occurring cyanohydrin, mandelonitrile, can also be synthesised from benzaldehyde. State what other reagents would be needed in this synthesis and show the mechanism that leads to the formation of the mandelonitrile. H OH CN mandelonitrile
27. Answer ALL parts of this question. (a) (b) (c) The secondary alcohol shown below can be synthesised by reacting benzaldehyde (C6HSCHO) with methyl magnesium bromide (CH3MgBr), followed by the addition of aqueous acid (H*/H₂O). H -C-CH3 I он Outline, using curly arrows, the mechanism of this reaction. Suggest, without giving details of mechanism, an alternative pair of starting materials (one is a carbonyl compound and the other is a Grignard reagent) that could also be used to synthesise this compound. The naturally occurring cyanohydrin, mandelonitrile, can also be synthesised from benzaldehyde. State what other reagents would be needed in this synthesis and show the mechanism that leads to the formation of the mandelonitrile. H OH CN mandelonitrile
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![27.
Answer ALL parts of this question.
(a)
(b)
(c)
The secondary alcohol shown below can be synthesised by reacting
benzaldehyde (C6HSCHO) with methyl magnesium bromide (CH3MgBr),
followed by the addition of aqueous acid (H*/H₂O).
H
-C-CH3
I
он
Outline, using curly arrows, the mechanism of this reaction.
Suggest, without giving details of mechanism, an alternative pair of starting
materials (one is a carbonyl compound and the other is a Grignard reagent)
that could also be used to synthesise this compound.
The naturally occurring cyanohydrin, mandelonitrile, can also be synthesised
from benzaldehyde. State what other reagents would be needed in this
synthesis and show the mechanism that leads to the formation of the
mandelonitrile.
H
OH
CN
mandelonitrile](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffd154053-d840-45c9-9afd-fe1847cfc3eb%2Fe34071fa-eac3-4ebe-aad4-8e10e6101830%2Fewkwxgc_processed.png&w=3840&q=75)
Transcribed Image Text:27.
Answer ALL parts of this question.
(a)
(b)
(c)
The secondary alcohol shown below can be synthesised by reacting
benzaldehyde (C6HSCHO) with methyl magnesium bromide (CH3MgBr),
followed by the addition of aqueous acid (H*/H₂O).
H
-C-CH3
I
он
Outline, using curly arrows, the mechanism of this reaction.
Suggest, without giving details of mechanism, an alternative pair of starting
materials (one is a carbonyl compound and the other is a Grignard reagent)
that could also be used to synthesise this compound.
The naturally occurring cyanohydrin, mandelonitrile, can also be synthesised
from benzaldehyde. State what other reagents would be needed in this
synthesis and show the mechanism that leads to the formation of the
mandelonitrile.
H
OH
CN
mandelonitrile
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