1. (a) Oxidation of 1-butanol with PCC will produce which of the following? 2-chlorobutanal butanone butanoic acid butanal (b) Which synthetic route is the best way to prepare ethyl isopropyl ether? CH3CH2OH + (CH3)2CHOH + H2SO4, 140 oC CH3CH2ONa + (CH3)2CHOH CH3CH2ONa + (CH3)2CHBr (CH3)2CHONa + CH3CH2Br
Organomagnesium compounds
The interaction of alkyl halide with Mg metal in a suitable ether solvent is the common method for the synthesis of the Grignard reagent.
Hydrolysis Grignard Reactions and Reduction
Organomagnesium halides are Grignard reagents. Francois Auguste Victor Grignard, a French chemist who received the Nobel Prize in Chemistry in 1912, created these highly useful reagents.
1. (a) Oxidation of 1-butanol with PCC will produce which of the following?
2-chlorobutanal |
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butanone |
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butanoic acid |
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butanal |
(b) Which synthetic route is the best way to prepare ethyl isopropyl ether?
CH3CH2OH + (CH3)2CHOH + H2SO4, 140 oC |
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CH3CH2ONa + (CH3)2CHOH |
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CH3CH2ONa + (CH3)2CHBr |
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(CH3)2CHONa + CH3CH2Br |
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