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27. An alternative step in the free radical chlorination mechanism, of methane might be as follows: What is the reason that this step is not observed? Consider the "propagation step-2" of th radical mechanism. Cl• + CH4 → CH3CI + H• 1. Cl• cannot approach the carbon atom close enough to form a bond because of steric interference from hydrogens 2. H• is not among the products of methane chlorination 3. Cl• can only bond to hydrogen atoms 4. this step is too endothermic as compared to alternatives 5. this step is too exothermic

27. An alternative step in the free radical chlorination mechanism, of methane might be as follows: What is the reason that this step is not observed? Consider the "propagation step-2" of th radical mechanism. Cl• + CH4 → CH3CI + H• 1. Cl• cannot approach the carbon atom close enough to form a bond because of steric interference from hydrogens 2. H• is not among the products of methane chlorination 3. Cl• can only bond to hydrogen atoms 4. this step is too endothermic as compared to alternatives 5. this step is too exothermic

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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27. An alternative step in the free radical chlorination mechanism, of methane might be as follows: What is the reason that this step is not observed? Consider the "propagation step-2" of the radical mechanism. Cl• + CH4 → CH3CI + H• 1. Cl• cannot approach the carbon atom close enough to form a bond because of steric interference from hydrogens 2. H• is not among the products of methane chlorination 3. Cl• can only bond to hydrogen atoms 4. this step is too endothermic as compared to alternatives 5. this step is too exothermic
Transcribed Image Text:27. An alternative step in the free radical chlorination mechanism, of methane might be as follows: What is the reason that this step is not observed? Consider the "propagation step-2" of the radical mechanism. Cl• + CH4 → CH3CI + H• 1. Cl• cannot approach the carbon atom close enough to form a bond because of steric interference from hydrogens 2. H• is not among the products of methane chlorination 3. Cl• can only bond to hydrogen atoms 4. this step is too endothermic as compared to alternatives 5. this step is too exothermic
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