25.7 Consider one of the cylindrical channels of inner diameter d that run through an isomerization catalyst, as shown in the figure below. A catalyst coats the inner walls of each channel. This catalyst promotes the isomerization of n-butane (n-C4H10, species A) to isobutene (n-C4H10, species B): n-C4H10 (8)→i-C4H10 (8) The gas phase above the channels contains mixture of A and B maintained at a constant composition of 60 mol % A and 40 mol% B. Gas-phase species A diffuses down a straight channel of diameter d = 0.10 cm and length L = 2.0 cm. The base of each channel is sealed. The surface reaction is rapid reaction so that the production rate of B is diffusion limited. The quiescent gas space in the channel consists of only species A and B. State three relevant assumptions for the mass-transfer pro- cess. Based on your assumptions, simplify the general differential equation for the mass transfer of species A, leaving the differential equation in terms of the ux N₁. b. Simplify Fick's ux equation for each coordinate of interest, and then express the simplified form of general differential equation from part (a) above in terms of the gas-phase concentration CA.

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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25.7 Consider one of the cylindrical channels of inner diameter
d that run through an isomerization catalyst, as shown in the
figure below. A catalyst coats the inner walls of each channel.
This catalyst promotes the isomerization of n-butane (n-C4H10,
species A) to isobutene (n-C4H10, species B):
n C4H10(g) →i – C4H10(g)
The gas phase above the channels contains mixture of A and B
maintained at a constant composition of 60 mol% A and 40
mol% B. Gas-phase species A diffuses down a straight channel
of diameter d = 0.10 cm and length L = 2.0 cm. The base of
each channel is sealed. The surface reaction is rapid reaction
so that the production rate of B is diffusion limited. The
quiescent gas space in the channel consists of only species A
and B.
State three relevant assumptions for the mass-transfer pro-
cess. Based on your assumptions, simplify the general
differential equation for the mass transfer of species A,
leaving the differential equation in terms of the ux N₁.
b. Simplify Fick's ux equation for each coordinate of interest,
and then express the simplified form of general differential
equation from part (a) above in terms of the gas-phase
concentration CA.
Transcribed Image Text:25.7 Consider one of the cylindrical channels of inner diameter d that run through an isomerization catalyst, as shown in the figure below. A catalyst coats the inner walls of each channel. This catalyst promotes the isomerization of n-butane (n-C4H10, species A) to isobutene (n-C4H10, species B): n C4H10(g) →i – C4H10(g) The gas phase above the channels contains mixture of A and B maintained at a constant composition of 60 mol% A and 40 mol% B. Gas-phase species A diffuses down a straight channel of diameter d = 0.10 cm and length L = 2.0 cm. The base of each channel is sealed. The surface reaction is rapid reaction so that the production rate of B is diffusion limited. The quiescent gas space in the channel consists of only species A and B. State three relevant assumptions for the mass-transfer pro- cess. Based on your assumptions, simplify the general differential equation for the mass transfer of species A, leaving the differential equation in terms of the ux N₁. b. Simplify Fick's ux equation for each coordinate of interest, and then express the simplified form of general differential equation from part (a) above in terms of the gas-phase concentration CA.
c. Specify relevant boundary conditions for the gas-phase
concentration CA.
Bulk gas phase
Inert support
-z = L = 2.0 cm
0.01-cm-diameter
(d) channels
Catalytic surface
A (g) → B (g)
-z = 0
Transcribed Image Text:c. Specify relevant boundary conditions for the gas-phase concentration CA. Bulk gas phase Inert support -z = L = 2.0 cm 0.01-cm-diameter (d) channels Catalytic surface A (g) → B (g) -z = 0
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