25. CS2(g) + 4 H2(g) → CHA(g) + 2 H₂S(g) at 298 K and 1 atm A. Calculate AHORxn for the above reaction, using the AH2, values in your references. B. Is this reaction exothermic or endothermic? C. Will it favor spontaneity based on enthalpy?
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
a.) ∆H°rxn can be calculated using the standard heat of formation ( ∆H°f ) values of each molecule involved in reaction.
b.) If ∆H°rxn is negative then reaction would be Exothermic.
If ∆H°rxn is positive then reaction would be Endothermic.
C) For reaction to be spontaneous in terms of enthalpy, there should be release in energy. That means ∆H°rxn should be negative.
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