None 24.In order to obtain accurate data to calculate the concentration of theH.PO (aq) solution, all of the indicators listed below can be used except14Titration Curve for Titration of 37 mL of0.10 mol/L H3PO4(aq) with NaOH(aq)* 1 point13-12-11109876.54-32O1-00102030 40506017670Volume of 0.10 mol/L NaOH(aq) (mL)bromocresol greenphenolphthaleinbromothymol bluethymol blue8-8090-8100

Based on the pH ranges and the equivalence points in the titration curve:Bromocresol green further…

Answered: 24.In order to obtain accurate data to…

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter11: Solutions

Section: Chapter Questions

Problem 26P

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A bottle of concentrated hydroiodic acid is 57% HI by weight and has a density of 1.70 g/mL. A solution of this strong and corrosive acid is made by adding exactly 10.0 mL to some water and diluting to 250.0 mL. If the information on the label is correct, what volume of 0.988 M NaOH is needed to neutralize the HI solution? Suggest an indicator for the titration.
A monoprotic organic acid that has a molar mass of 176.1 g/mol is synthesized. Unfortunately, the acid produced is not completely pure. In addition, it is not soluble in water. A chemist weighs a 1.8451-g sample of the impure acid and adds it to 100.0 mL of 0.1050 M NaOH. The acid is soluble in the NaOH solution and reacts to consume most of the NaOH. The amount of excess NaOH is determined by titration: It takes 3.28 mL of 0.0970 M HCl to neutralize the excess NaOH. What is the purity of the original acid, in percent?
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
Follow the directions of Question 64. Consider two beakers: Beaker A has a weak acid(K a=1105). Beaker B has HCI. The volume and molarity of each acid in the beakers are the same. Both acids are to be titrated with a 0.1 M solution of NaOH. (a) Before titration starts (at zero time), the pH of the solution in Beaker A is the pH of the solution in Beaker B. (b) At half-neutralization (halfway to the equivalence point), the pH of the solution in Beaker A the pH of the solution in Beaker B. (c) When each solution has reached its equivalence point, the pH of the solution in Beaker A the pH of the solution in Beaker B. (d) At the equivalence point, the volume of NaOH used to titrate HCI in Beaker B the volume of NaOH used to titrate the weak acid in Beaker A.
Consider the following two acids: In two separate experiments the pH was measured during the titration of 5.00 mmol of each acid with 0.200 M NaOH. Each experiment showed only one stoichiometric point when the data were plotted. In one experiment the stoichiometric point was at 25.00 mL added NaOH, and in the other experiment the stoichiometric point was at 50.00 mL NaOH. Explain these results. (See Exercise 113.)
A 10.00-g sample of the ionic compound NaA, where A is the anion of a weak acid, was dissolved in enough water to make 100.0 mL of solution and was then titrated with 0.100 M HCl. After 500.0 mL HCl was added, the pH was 5.00. The experimenter found that 1.00 L of 0.100 M HCl was required to reach the stoichiometric point of the titration. a. What is the molar mass of NaA? b. Calculate the pH of the solution at the stoichiometric point of the titration.
. Which component of a buffered solution is capable of combining with an added strong acid? Using your example from Exercise 60, show how this component would react with added HC1.
If 55 mg of lead(II) sulfate is placed in 250 mL of pure water, does all of it dissolve? If not, how much dissolves?
In Exercise 12.49, what is the allowed concentration of AgCl in g per 100 g of water? The Safe Drinking Water Act of 1974 established the maximum permitted concentration of silver ion at 0.05 ppm. What is the concentration of Ag+ in parts per million in a saturated solution of AgCl? (NOTE: 1 ppm = 1 mgofsolute/L of solution.)
Isocyanic acid (HNCO) can be prepared by heating sodium cyanate in the presence of solid oxalic acid according to the equation 2NaOCN(s)+H2C2O4(s)2HNCO(l)+Na2C2O4(s) Upon isolating pure HNCO(l), an aqueous solution of HNCO can be prepared by dissolving the liquid HNCO in water. What is the pH of a l00.-mL solution of HNCO prepared from the reaction of 10.0 g each of NaOCN and H2C2O4, assuming all of the HNCO produced is dissolved in solution? (Ka of HNCO = 1.2 l04.)
. How is the strength of an acid related to the fact that a competition for protons exists in aqueous solution between water molecules and the anion of the acid?
An acid is titrated with NaOH. The following beakers are illustrations of the contents of the beaker at various times during the titration. These are presented out of order. Note: Counter-ions and water molecules have been omitted from the illustrations for clarity. (a) (b) (c) (d) (e) a. Is the acid a weak or strong acid? How can you tell? b. Arrange the beakers in order of what the contents would look like as the titration progresses. c. For which beaker would pH = pKa? Explain your answer. d. Which beaker represents the equivalence point of the titration? Explain your answer. e. For which beaker would the Ka value for the acid not be necessary to determine the pH? Explain your answer.

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