24. Define a) chiral chromatography. b) adsorption chromatography.

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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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24. Define
a) chiral chromatography.
b) adsorption chromatography.
25. Explain the difference between gel filtration and gel permeation.
27. Indicate the order in which the following compounds would be
eluted from an HPLC column containing a reversed-phase packing:
(a) benzene, diethyl ether, n-hexane.
(b) acetone, dichloroethane, acetamide.
28. Describe the fundamental difference between ion-exchange and
size-exclusion chromatography.
29. What types of species can be separated by HPLC but not by GC?
30. Compare the advantages of HPLC and GC instruments.
32. Briefly describe or define
(a) oxidation.
(b) reduction
(c) reducing agent.
(d) oxidizing agent.
(e) salt bridge.
glish (United States)
W
DELL
Transcribed Image Text:Paragraph Styles 24. Define a) chiral chromatography. b) adsorption chromatography. 25. Explain the difference between gel filtration and gel permeation. 27. Indicate the order in which the following compounds would be eluted from an HPLC column containing a reversed-phase packing: (a) benzene, diethyl ether, n-hexane. (b) acetone, dichloroethane, acetamide. 28. Describe the fundamental difference between ion-exchange and size-exclusion chromatography. 29. What types of species can be separated by HPLC but not by GC? 30. Compare the advantages of HPLC and GC instruments. 32. Briefly describe or define (a) oxidation. (b) reduction (c) reducing agent. (d) oxidizing agent. (e) salt bridge. glish (United States) W DELL
36. Generate equilibrium constant expressions for the following
reactions. Calculate numerical values for Keg.
57351 6
+0.771
A Fe + V* R + V*
-0.255
Vo* + 2H" + e=V* + H,O
VOH), 2H +e=VO" + 3H,O
+0.337
2VO- Uo,*+
B 2V(OH),+ U** =
4H 0
+1.00
UO,+ 4H + 2e=U** + 2H,O
+0.334
37- Calculate the potential required to intiate deposition of copper
from a solution that is 0.01 M in CuS04 and contains sufficient
H2SO4 to give a pH of 4.0O.
ENCIAg +0.337 V (right)
EH,0 =
Cu + 2e Cu(s)
= +1.229 V (left)
0, + 4H + 4e 2H,0
Transcribed Image Text:36. Generate equilibrium constant expressions for the following reactions. Calculate numerical values for Keg. 57351 6 +0.771 A Fe + V* R + V* -0.255 Vo* + 2H" + e=V* + H,O VOH), 2H +e=VO" + 3H,O +0.337 2VO- Uo,*+ B 2V(OH),+ U** = 4H 0 +1.00 UO,+ 4H + 2e=U** + 2H,O +0.334 37- Calculate the potential required to intiate deposition of copper from a solution that is 0.01 M in CuS04 and contains sufficient H2SO4 to give a pH of 4.0O. ENCIAg +0.337 V (right) EH,0 = Cu + 2e Cu(s) = +1.229 V (left) 0, + 4H + 4e 2H,0
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