24. Based on your understanding of the relationships between the structures and physical properties of elements and compounds, which of the substances (Table 1) is most likely a covalent network solid? Why? Explain your reasoning in at least two (2) sentences.

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Chapter1: Chemical Foundations
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Table 1: The physical characteristics of six unknown samples.
Sample B
> 1700°C
7
Insoluble
Insulator
Property
Melting Point
Hardness
Solubility (H₂O)
Electrical Conductivity
Sample A
<-200°C
N/A
Soluble
Insulator
Sample C
< 180°C
N/A
Insoluble
Insulator
Sample D
> 600°C
3
Insoluble
Conductor
Sample E
> 700°C
9
Soluble
Aqueous Conductor
Transcribed Image Text:Table 1: The physical characteristics of six unknown samples. Sample B > 1700°C 7 Insoluble Insulator Property Melting Point Hardness Solubility (H₂O) Electrical Conductivity Sample A <-200°C N/A Soluble Insulator Sample C < 180°C N/A Insoluble Insulator Sample D > 600°C 3 Insoluble Conductor Sample E > 700°C 9 Soluble Aqueous Conductor
24. Based on your understanding of the relationships between the structures and physical properties of
elements and compounds, which of the substances (Table 1) is most likely a covalent network solid?
Why? Explain your reasoning in at least two (2) sentences.
Transcribed Image Text:24. Based on your understanding of the relationships between the structures and physical properties of elements and compounds, which of the substances (Table 1) is most likely a covalent network solid? Why? Explain your reasoning in at least two (2) sentences.
Expert Solution
Step 1

Covalent network solids consist of atoms covalently bonded into a three-dimensional network or layers of two-dimensional networks.

The most commonly known covalent network solids are diamond, graphite, silicon dioxide, and fullerene.

Now, the physical properties of covalent network solids are-

  • Due to the strength of covalent bonds, covalent network solids have high melting points (higher than 1000oC) .
  • Three-dimensional network solids (such as diamond or silicon dioxide) are hard and rigid, while two-dimensional network solids (such as graphite) are soft due to the ease with which the network layers can slide over each other.
  • All covalent network solids are insoluble in water and are poor conductors of electricity (except graphite) due to the absence of free electrons.
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