23. metric isomerism. If geometric isomers ex1s many there are. (a) tetrahedral [Cd(H2O)2C12], (b) squ nar [IrCl,(PH3)2] , (c) octahedral [ Fe(0-phen)2C12]*. metric the isomers be op 23.44 Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, deter- mine how many there are. (a) [Rh(bipy) (0-phen)2]³*, (b(Co(NH3);(bipy)Br]2+, (c) square-planar [Pd(en)(CN)2]. 23.45 Determine if each of the following metal complexes is chiral and therefore has an optical isomer: (a) tetrahedral [Zn(H,O),Cl,], (b) octahedral trans-[Ru(bipy),Cl,], (c) octa- hedral cis-[Ru(bipy),Cl,]. 23.43 Determine if each of the follov 3+ 23.46 Determine if each of the following metal complexes is chi- ral and therefore has an optical isomer: (a) square planar [Pd(en)(CN),), (b) octahedral [Ni(en)(NH,),]²+, (c) octahe- dral cis-[V(en),CIB1]. Color and Magnetism in Coordination Chemistry; Crystal-Field Theory (Sections 23.5 and 23.6) 23.47 (a) If a complex absorbs light at 610 nm, what color would you expect the complex to be? (b) What is the energy in joules of a photon with a wavelength of 610 nm? (c) What is the energy of this absorption in kJ/mol? 23.48 (a) A complex absorbs photons with an energy of 4.51 x 10 19 J. What is the wavelength of these photons? (b) If this is the only place in the visible spectrum where the complex absorbs light, what color would you the complex to be? 23.49 Identify each of the foll either diama

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23.
metric isomerism. If geometric isomers ex1s
many there are. (a) tetrahedral [Cd(H2O)2C12], (b) squ
nar [IrCl,(PH3)2] , (c) octahedral [ Fe(0-phen)2C12]*.
metric
the isomers be op
23.44 Determine if each of the following complexes exhibits
geometric isomerism. If geometric isomers exist, deter-
mine how many there are. (a) [Rh(bipy) (0-phen)2]³*,
(b(Co(NH3);(bipy)Br]2+, (c) square-planar [Pd(en)(CN)2].
23.45 Determine if each of the following metal complexes is
chiral and therefore has an optical isomer: (a) tetrahedral
[Zn(H,O),Cl,], (b) octahedral trans-[Ru(bipy),Cl,], (c) octa-
hedral cis-[Ru(bipy),Cl,].
23.43 Determine if each of the follov
3+
23.46 Determine if each of the following metal complexes is chi-
ral and therefore has an optical isomer: (a) square planar
[Pd(en)(CN),), (b) octahedral [Ni(en)(NH,),]²+, (c) octahe-
dral cis-[V(en),CIB1].
Color and Magnetism in Coordination Chemistry;
Crystal-Field Theory (Sections 23.5 and 23.6)
23.47 (a) If a complex absorbs light at 610 nm, what color would
you expect the complex to be? (b) What is the energy in
joules of a photon with a wavelength of 610 nm? (c) What
is the energy of this absorption in kJ/mol?
23.48 (a) A complex absorbs photons with an energy of
4.51 x 10 19 J. What is the wavelength of these photons?
(b) If this is the only place in the visible spectrum where
the complex absorbs light, what color would you
the complex to be?
23.49 Identify each of the foll
either diama
Transcribed Image Text:23. metric isomerism. If geometric isomers ex1s many there are. (a) tetrahedral [Cd(H2O)2C12], (b) squ nar [IrCl,(PH3)2] , (c) octahedral [ Fe(0-phen)2C12]*. metric the isomers be op 23.44 Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, deter- mine how many there are. (a) [Rh(bipy) (0-phen)2]³*, (b(Co(NH3);(bipy)Br]2+, (c) square-planar [Pd(en)(CN)2]. 23.45 Determine if each of the following metal complexes is chiral and therefore has an optical isomer: (a) tetrahedral [Zn(H,O),Cl,], (b) octahedral trans-[Ru(bipy),Cl,], (c) octa- hedral cis-[Ru(bipy),Cl,]. 23.43 Determine if each of the follov 3+ 23.46 Determine if each of the following metal complexes is chi- ral and therefore has an optical isomer: (a) square planar [Pd(en)(CN),), (b) octahedral [Ni(en)(NH,),]²+, (c) octahe- dral cis-[V(en),CIB1]. Color and Magnetism in Coordination Chemistry; Crystal-Field Theory (Sections 23.5 and 23.6) 23.47 (a) If a complex absorbs light at 610 nm, what color would you expect the complex to be? (b) What is the energy in joules of a photon with a wavelength of 610 nm? (c) What is the energy of this absorption in kJ/mol? 23.48 (a) A complex absorbs photons with an energy of 4.51 x 10 19 J. What is the wavelength of these photons? (b) If this is the only place in the visible spectrum where the complex absorbs light, what color would you the complex to be? 23.49 Identify each of the foll either diama
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