23. metric isomerism. If geometric isomers ex1s many there are. (a) tetrahedral [Cd(H2O)2C12], (b) squ nar [IrCl,(PH3)2] , (c) octahedral [ Fe(0-phen)2C12]*. metric the isomers be op 23.44 Determine if each of the following complexes exhibits geometric isomerism. If geometric isomers exist, deter- mine how many there are. (a) [Rh(bipy) (0-phen)2]³*, (b(Co(NH3);(bipy)Br]2+, (c) square-planar [Pd(en)(CN)2]. 23.45 Determine if each of the following metal complexes is chiral and therefore has an optical isomer: (a) tetrahedral [Zn(H,O),Cl,], (b) octahedral trans-[Ru(bipy),Cl,], (c) octa- hedral cis-[Ru(bipy),Cl,]. 23.43 Determine if each of the follov 3+ 23.46 Determine if each of the following metal complexes is chi- ral and therefore has an optical isomer: (a) square planar [Pd(en)(CN),), (b) octahedral [Ni(en)(NH,),]²+, (c) octahe- dral cis-[V(en),CIB1]. Color and Magnetism in Coordination Chemistry; Crystal-Field Theory (Sections 23.5 and 23.6) 23.47 (a) If a complex absorbs light at 610 nm, what color would you expect the complex to be? (b) What is the energy in joules of a photon with a wavelength of 610 nm? (c) What is the energy of this absorption in kJ/mol? 23.48 (a) A complex absorbs photons with an energy of 4.51 x 10 19 J. What is the wavelength of these photons? (b) If this is the only place in the visible spectrum where the complex absorbs light, what color would you the complex to be? 23.49 Identify each of the foll either diama
Lipids
The heterogeneous classes of organic compounds that are not water-soluble but are dissolved in organic solvents that are non-polar in nature are termed lipids. They are a long chain of fatty acids and esters of alcohols. Lipids are generally seen in several plants, microorganisms, and animals. They are utilized as insulation, components of the cell membrane, hormones, and molecules for the storage of energy.
Glycerophospholipid
Glycerophospholipid is the most abundantly occuring phospholipids found in the biological membranes. Lipids include a group of organic compounds like fats, hormones, oils, waxes, vitamins etc. They are non-polar molecules and are insoluble in water. Lipids play an important role in biological systems. They are the building blocks of our cell membranes, store energy and are involved in signaling.
Structure Of Camphor
A terpene with the molecular formula of C10H16O is a waxy, white color solid known as camphor. It is flammable. It also possesses a very pungent taste and a strong odor. There are various sources for extracting camphor from natural products such as the wood of the tree of camphor laurel. Sublimation of wood and steam distillation are some of the methods involved in obtaining camphor.
Glycolipid In Organic Chemistry
Glycolipids are lipids that are an important class of organic compounds in chemistry that have simple to complex applications. They contain carbohydrates, fatty acids, sphingolipids or a glycerol group. In other words, they are the modifications of lipids like acylglycerols, prenols and ceramides. They are all part of a wider group of compounds known as glycoconjugates.
Diterpenoid
The terpenoid class includes diterpenoids, which are chemical compounds with 20 carbon atoms. They are made up of four isoprene units and are derived from geranylgeraniol, a C20 precursor. They have a C20H32 basic structure. These characteristics distinguish diterpenoids from simple terpenes, which have just 10 carbon atoms.
23.44 include drawings
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