23 The equilibrium constant Kp for the reaction P PCI5(g) = PCI3(g) + Cl2(8) is 1.05 at 250°C. The reaction starts with a mixture of PCI5, PCI3, and Cl2 at pressures 0.177 atm, 0.223 atm, and 0.111 atm, respectively, at 250°C. When the mixture comes to equilibrium at that tem- perature, which pressures will have decreased and which will have increased? Explain why.

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14.23 The equilibrium constant Kp for the reaction
PCI5(8) = PCI3(g) + Cl2(g)
is 1.05 at 250°C. The reaction starts with a mixture
of PCI5, PCI3, and Cl2 at pressures 0.177 atm,
0.223 atm, and 0.111 atm, respectively, at 250°C.
When the mixture comes to equilibrium at that tem-
perature, which pressures will have decreased and
which will have increased? Explain why.
14
Transcribed Image Text:14.23 The equilibrium constant Kp for the reaction PCI5(8) = PCI3(g) + Cl2(g) is 1.05 at 250°C. The reaction starts with a mixture of PCI5, PCI3, and Cl2 at pressures 0.177 atm, 0.223 atm, and 0.111 atm, respectively, at 250°C. When the mixture comes to equilibrium at that tem- perature, which pressures will have decreased and which will have increased? Explain why. 14
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