22. The following problem pertains to AgBr(s), Ksp = 5.0 x 10-13, Hg»Br2(s), Ksp 1.3 x 10-22, and [Ag(S2O3)2]³-, Kr= 2.9 × 1013. A. (i) Include state symbols. Write the reaction for dissolving (dissolution) of AgBr(s) into its aqueous ions. (ii) Include state symbols. Hint: recall mercury forms a Hg22+ ion. Write the reaction for dissolving (dissolution) of Hg,Br2(s) into its aqueous ions. (iii) Write the formation constant expression (Kr) for the complex ion [Ag(S2O3)2]³-
22. The following problem pertains to AgBr(s), Ksp = 5.0 x 10-13, Hg»Br2(s), Ksp 1.3 x 10-22, and [Ag(S2O3)2]³-, Kr= 2.9 × 1013. A. (i) Include state symbols. Write the reaction for dissolving (dissolution) of AgBr(s) into its aqueous ions. (ii) Include state symbols. Hint: recall mercury forms a Hg22+ ion. Write the reaction for dissolving (dissolution) of Hg,Br2(s) into its aqueous ions. (iii) Write the formation constant expression (Kr) for the complex ion [Ag(S2O3)2]³-
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Solubility and Formation Reactions
#### Problem Statement:
The following problem pertains to different sparingly soluble compounds and a complex ion:
- Silver bromide \( \text{AgBr(s)} \), solubility product \( K_{\text{sp}} = 5.0 \times 10^{-13} \)
- Mercury(I) bromide \( \text{Hg}_2\text{Br}_2(\text{s}) \), solubility product \( K_{\text{sp}} = 1.3 \times 10^{-22} \)
- Tetrathiosilver(II) ion \( [\text{Ag}(\text{S}_2\text{O}_3)_2]^{3-} \), formation constant \( K_f = 2.9 \times 10^{13} \)
##### A. Write the required chemical equations and expressions:
**(i) Write the reaction for dissolving \( \text{AgBr(s)} \) into its aqueous ions. Include state symbols.**
\[ \text{AgBr(s)} \rightarrow \text{Ag}^+(\text{aq}) + \text{Br}^-(\text{aq}) \]
**(ii) Write the reaction for dissolving \( \text{Hg}_2\text{Br}_2(\text{s}) \) into its aqueous ions. Include state symbols. Hint: recall mercury forms a \( \text{Hg}_2^{2+} \) ion.**
\[ \text{Hg}_2\text{Br}_2(\text{s)} \rightarrow \text{Hg}_2^{2+}(\text{aq}) + 2\text{Br}^-(\text{aq}) \]
**(iii) Write the formation constant expression \( (K_f) \) for the complex ion \( [\text{Ag}(\text{S}_2\text{O}_3)_2]^{3-} \).**
\[
K_f = \frac{ \left[ \text{Ag}(\text{S}_2\text{O}_3)_2^{3-} \right]}{ \left[ \text{Ag}^+ \right] \left[ \text{S}_2\text{O}_3^{2-} \right]^2 }
\]
This information is essential for understanding the solubility and](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fad75d3c3-f925-415c-aa85-2c90219f0688%2Fee41972e-51a3-42c5-a580-bb0c5256252c%2F3hjy17h_processed.png&w=3840&q=75)
Transcribed Image Text:### Solubility and Formation Reactions
#### Problem Statement:
The following problem pertains to different sparingly soluble compounds and a complex ion:
- Silver bromide \( \text{AgBr(s)} \), solubility product \( K_{\text{sp}} = 5.0 \times 10^{-13} \)
- Mercury(I) bromide \( \text{Hg}_2\text{Br}_2(\text{s}) \), solubility product \( K_{\text{sp}} = 1.3 \times 10^{-22} \)
- Tetrathiosilver(II) ion \( [\text{Ag}(\text{S}_2\text{O}_3)_2]^{3-} \), formation constant \( K_f = 2.9 \times 10^{13} \)
##### A. Write the required chemical equations and expressions:
**(i) Write the reaction for dissolving \( \text{AgBr(s)} \) into its aqueous ions. Include state symbols.**
\[ \text{AgBr(s)} \rightarrow \text{Ag}^+(\text{aq}) + \text{Br}^-(\text{aq}) \]
**(ii) Write the reaction for dissolving \( \text{Hg}_2\text{Br}_2(\text{s}) \) into its aqueous ions. Include state symbols. Hint: recall mercury forms a \( \text{Hg}_2^{2+} \) ion.**
\[ \text{Hg}_2\text{Br}_2(\text{s)} \rightarrow \text{Hg}_2^{2+}(\text{aq}) + 2\text{Br}^-(\text{aq}) \]
**(iii) Write the formation constant expression \( (K_f) \) for the complex ion \( [\text{Ag}(\text{S}_2\text{O}_3)_2]^{3-} \).**
\[
K_f = \frac{ \left[ \text{Ag}(\text{S}_2\text{O}_3)_2^{3-} \right]}{ \left[ \text{Ag}^+ \right] \left[ \text{S}_2\text{O}_3^{2-} \right]^2 }
\]
This information is essential for understanding the solubility and
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