2.6 (C)-\) • (c) Show that the grand canonical partition function of an ideal gas can be written as V ZG = exp 23 Luo for AI P S

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•2.6 (c)-(f)
• (c) Show that the grand canonical partition function of an ideal gas
can be written as
Zg = exp
expleßu
23
(d) Use the expression for Zg to calculate the mean value for N, P, S,
and show that PV = NkgT and that the Gibbs-Duhem equation gives
E = ?NkgT.
Transcribed Image Text:•2.6 (c)-(f) • (c) Show that the grand canonical partition function of an ideal gas can be written as Zg = exp expleßu 23 (d) Use the expression for Zg to calculate the mean value for N, P, S, and show that PV = NkgT and that the Gibbs-Duhem equation gives E = ?NkgT.
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