2.21 Combinations of platinum(II) cations, ammonia molecules, thiocyanate anions, and ammonium cations result in the formation of a series of five coordination compounds. (a) Write the modern formulas for the members of this series. (Hint: Not all five compounds contain each of the components.) (b) Name the compound that contains (i) the cation of highest charge and (ii) the anion of highest charge. (c) Write the formula for the neutral member of this series as Werner would have written it. Assuming that the thiocyanate ion always binds through its sulfur atom and that platinum(II) has a square planar coordination sphere, how many isomers would this compound have?
2.21 Combinations of platinum(II) cations, ammonia molecules, thiocyanate anions, and ammonium cations result in the formation of a series of five coordination compounds. (a) Write the modern formulas for the members of this series. (Hint: Not all five compounds contain each of the components.) (b) Name the compound that contains (i) the cation of highest charge and (ii) the anion of highest charge. (c) Write the formula for the neutral member of this series as Werner would have written it. Assuming that the thiocyanate ion always binds through its sulfur atom and that platinum(II) has a square planar coordination sphere, how many isomers would this compound have?
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 105QRT
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Transcribed Image Text:*2.21 Combinations of platinum(II) cations, ammonia molecules, thiocyanate anions,
and ammonium cations result in the formation of a series of five coordination
compounds.
(a) Write the modern formulas for the members of this series. (Hint: Not all five
compounds contain each of the components.)
(b) Name the compound that contains (i) the cation of highest charge and (ii) the
anion of highest charge.
(c) Write the formula for the neutral member of this series as Werner would have
written it. Assuming that the thiocyanate ion always binds through its sulfur
atom and that platinum(II) has a square planar coordination sphere, how
many isomers would this compound have?
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