2. The scheme below illustrates the synthesis of a cage-annulated ether conductedby Marchand and coworkers which utilizes a Baeyer-Villiger oxidation.mCPBADCMIntermediate11. LAH2. H₂O, HCIIntermediate2Tosyl Chloride(TSCI)HN.a. Provide the structures of intermediate 1 and intermediate 2.b. Provide a complete arrow pushing mechanism for each reaction. You mayabbreviate the structure by only utilizing the front cyclopentane ring in yourmechanisms.

mcpba acts as oxidant for the epoxidation of ketones, leading to the formation of ester (lactone in…

2. The scheme below illustrates the synthesis of a cage-annulated ether conducted by Marchand and coworkers which utilizes a Baeyer-Villiger oxidation. mCPBA DCM Intermediate 1 1. LAH 2. H₂O, HCI Intermediate 2 Tosyl Chloride (TSCI) a. Provide the structures of intermediate 1 and intermediate 2. b. Provide a complete arrow pushing mechanism for each reaction. You may abbreviate the structure by only utilizing the front cyclopentane ring in your mechanisms.

2. The scheme below illustrates the synthesis of a cage-annulated ether conducted by Marchand and coworkers which utilizes a Baeyer-Villiger oxidation. mCPBA DCM Intermediate 1 1. LAH 2. H₂O, HCI Intermediate 2 Tosyl Chloride (TSCI) a. Provide the structures of intermediate 1 and intermediate 2. b. Provide a complete arrow pushing mechanism for each reaction. You may abbreviate the structure by only utilizing the front cyclopentane ring in your mechanisms.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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