2. The data below were collected for the following reaction: 2A(g) + 2B(g) à C(g) + 2D(g) for the initial rate of consumption of A at 1100K. [A]o [B] Initial Rate (M/s) 0.00500 0.00250 0.0030 0.0150 0.00250 0.0090 0.0150 0.0100 0.036 a. Write the expression for the differential rate law and calculate the value of the rate constant (include units). b. What is the overall order of reaction? c. Calculate the initial rate of this reaction at 1100K when [A] [B]= 0.00800 M.

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Chapter1: Chemical Foundations
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Solutions to question 2 please
1. Consider the reaction 2CO(g) + O₂(g) = 2CO₂(g).
a. Calculate the Kp at 25.0°C for this reaction using
the following standard free energies of formation
values at 25.0°C (AG°f(CO)= -137 kJ/mol, AG°f
(CO,)= -394 kJ/mol).
b. What is the AG (in kJ/mol) at 25.0°C if 0.855 atm
CO, 0.125 atm O₂ and 0.183 atm CO₂ are
present?
2
c. Calculate the Kp at 100.0° C for this reaction
using the van't Hoff equation and following
standard enthalpies of formation (AH, (CO)=
-110.5 kJ/mol, AH° (CO₂) = -393.5 kJ/mol)
2. The data below were collected for the following
reaction: 2A(g) + 2B(g) à C(g) + 2D(g) for the initial
rate of consumption of A at 1100K.
[A]o [B] Initial Rate (M/s)
0.00500 0.00250
0.0030
0.0150 0.00250
0.0090
0.0150 0.0100
0.036
a. Write the expression for the differential rate law
and calculate the value of the rate constant
(include units).
b. What is the overall order of reaction?
c. Calculate the initial rate of this reaction at 1100K
when [A] [B]=0.00800 M.
Transcribed Image Text:1. Consider the reaction 2CO(g) + O₂(g) = 2CO₂(g). a. Calculate the Kp at 25.0°C for this reaction using the following standard free energies of formation values at 25.0°C (AG°f(CO)= -137 kJ/mol, AG°f (CO,)= -394 kJ/mol). b. What is the AG (in kJ/mol) at 25.0°C if 0.855 atm CO, 0.125 atm O₂ and 0.183 atm CO₂ are present? 2 c. Calculate the Kp at 100.0° C for this reaction using the van't Hoff equation and following standard enthalpies of formation (AH, (CO)= -110.5 kJ/mol, AH° (CO₂) = -393.5 kJ/mol) 2. The data below were collected for the following reaction: 2A(g) + 2B(g) à C(g) + 2D(g) for the initial rate of consumption of A at 1100K. [A]o [B] Initial Rate (M/s) 0.00500 0.00250 0.0030 0.0150 0.00250 0.0090 0.0150 0.0100 0.036 a. Write the expression for the differential rate law and calculate the value of the rate constant (include units). b. What is the overall order of reaction? c. Calculate the initial rate of this reaction at 1100K when [A] [B]=0.00800 M.
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