1. Solve the following queries (parts a), b), & c)) dealing with volumetric analysis. Make sure you show complete procedures a) Ammonia reacts with hypobromite, OBr, by the reaction: 2NH3 + 30Br→ N₂ + 3Br + 3H₂O What is the molarity of a hypobromite solution if 1.00 mL of the OBr - solution reacts with 1.69 mg of NH3? b) A 0.8040-g sample of an iron ore is dissolved in acid. The iron is then reduced to Fe2+ and titrated with 47.22 mL of 0.02242 M KMnO4 solution. Calculate the results of this analysis in terms of (a) % Fe and (b) % Fe3O4. The reaction is the following one: MnO4 +5Fe²+ + 8H+ → Mn²+ +5Fe³+ + 4H₂O c) A solution of HCIO4 was standardized by dissolving 0.4008 g of primary-standard- grade HgO in a solution of KBr: HgO(s) + 4Br + H₂O → HgBr?¯ + 2OH- The liberated OH consumed 43.75 mL of the acid. Calculate the molar concentration of the HCIO4.

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show full & complete procedure. Please answer parts a), b) & c). Note they are subparts of the same question 

1. Solve the following queries (parts a), b), & c)) dealing with volumetric analysis. Make sure you show complete
procedures
a) Ammonia reacts with hypobromite, OBr", by the reaction:
2NH3 + 30Br ¯➜ N₂ + 3Br ¯ + 3H₂O
What is the molarity of a hypobromite solution if 1.00 mL of the OBr - solution
reacts with 1.69 mg of NH3?
b) A 0.8040-g sample of an iron ore is dissolved in acid. The iron is then reduced to
Fe²+ and titrated with 47.22 mL of 0.02242 M KMnO4 solution. Calculate the
results of this analysis in terms of (a) % Fe and (b) % Fe3O4. The reaction is the
following one:
MnO +5Fe²+ + 8H+ → Mn²+ + 5Fe³+ + 4H₂0
c) A solution of HCIO4 was standardized by dissolving 0.4008 g of primary-standard-
grade HgO in a solution of KBr:
HgO(s) + 4Br¯ + H₂O → HgBr²¯ +20H¯
The liberated OH consumed 43.75 mL of the acid. Calculate the molar
concentration of the HCIO4.
Transcribed Image Text:1. Solve the following queries (parts a), b), & c)) dealing with volumetric analysis. Make sure you show complete procedures a) Ammonia reacts with hypobromite, OBr", by the reaction: 2NH3 + 30Br ¯➜ N₂ + 3Br ¯ + 3H₂O What is the molarity of a hypobromite solution if 1.00 mL of the OBr - solution reacts with 1.69 mg of NH3? b) A 0.8040-g sample of an iron ore is dissolved in acid. The iron is then reduced to Fe²+ and titrated with 47.22 mL of 0.02242 M KMnO4 solution. Calculate the results of this analysis in terms of (a) % Fe and (b) % Fe3O4. The reaction is the following one: MnO +5Fe²+ + 8H+ → Mn²+ + 5Fe³+ + 4H₂0 c) A solution of HCIO4 was standardized by dissolving 0.4008 g of primary-standard- grade HgO in a solution of KBr: HgO(s) + 4Br¯ + H₂O → HgBr²¯ +20H¯ The liberated OH consumed 43.75 mL of the acid. Calculate the molar concentration of the HCIO4.
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