2. Sulfuryl chloride (SO,Cl,) decomposes to give sulfur dioxide and and diatomic chlorine (all gases). a. Calculate the enthalpy of formation for this reaction using Hess's Law. The one value you can't find easily is that of SO,Cl, – it's Hf= -391.4 kJ/mol. b. 243 grams of SO,Cl, are placed in a 2.5 L flask and the temperature is brought to 375 deg. C. The concentration of Cl, is measured and reaches a constant value of 0.159M. What is the equilibrium constant for this reaction? Which way would the equilibrium shift if the temperature was с. raised? d. Write 3 brief sentences – one that gives information on what the value of DH says about the reaction, one on what the value of K says about the reaction and a third sentence about express if the values for part a and part b are corroborative or completely separate values that give us completely different information. e. 5 grams of Cl, are added to the reaction in part b after equilibrium had been established. What are the new equilibrium concentrations once equilibrium has been reestablished?
2. Sulfuryl chloride (SO,Cl,) decomposes to give sulfur dioxide and and diatomic chlorine (all gases). a. Calculate the enthalpy of formation for this reaction using Hess's Law. The one value you can't find easily is that of SO,Cl, – it's Hf= -391.4 kJ/mol. b. 243 grams of SO,Cl, are placed in a 2.5 L flask and the temperature is brought to 375 deg. C. The concentration of Cl, is measured and reaches a constant value of 0.159M. What is the equilibrium constant for this reaction? Which way would the equilibrium shift if the temperature was с. raised? d. Write 3 brief sentences – one that gives information on what the value of DH says about the reaction, one on what the value of K says about the reaction and a third sentence about express if the values for part a and part b are corroborative or completely separate values that give us completely different information. e. 5 grams of Cl, are added to the reaction in part b after equilibrium had been established. What are the new equilibrium concentrations once equilibrium has been reestablished?
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter5: Principles Of Chemical Reactivity: Energy And Chemical Reactions
Section: Chapter Questions
Problem 62PS: An important step in the production of sulfuric acid is the oxidation of SO2 to SO3. SO2(g) + O2(g)...
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