2. Start with the four possible two-electron spin functions: 1 Va = a (1) a (2) = Wc= [a(1)B(2) + B(1)a(2)] √2 1 √2 Va [a(1)B(2) - B(1)a(2)] = b = B(1)B(2) Evaluate each of these with the total z-component spin operator, Sz total = Sz1 + $zz to find the value of the total spin, which is the eigenvalue in Sz total(1,2)= Sz total (1,2). Keep in mind that S₂₁ (1) = 1/2 and S₂1 B(1) = -1/2; and that (A + B) = A + By.

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2. Start with the four possible two-electron spin functions:
1
Va = a (1) a (2)
√2
Vc= [a(1)B(2) + B(1)a (2)]
=
Va
b = B(1)B(2)
la(1)B(2) - B(1)a(2)]
Evaluate each of these with the total z-component spin operator, Sz total = Sz1 + Śzz to find
the value of the total spin, which is the eigenvalue in Sz total(1,2)= Sz total(1,2). Keep
in mind that S₂1 a(1) = 1/2 and S₂1 B(1) = -1/2; and that (A + B) = A + Bw.
=
Transcribed Image Text:2. Start with the four possible two-electron spin functions: 1 Va = a (1) a (2) √2 Vc= [a(1)B(2) + B(1)a (2)] = Va b = B(1)B(2) la(1)B(2) - B(1)a(2)] Evaluate each of these with the total z-component spin operator, Sz total = Sz1 + Śzz to find the value of the total spin, which is the eigenvalue in Sz total(1,2)= Sz total(1,2). Keep in mind that S₂1 a(1) = 1/2 and S₂1 B(1) = -1/2; and that (A + B) = A + Bw. =
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