2. Sketch (as accurately as you can) steady state i vs E curves for solutions prepared from: a) 1 mM SnV and 2 mM Cel b) 1 mM Fell and 2 mM Celv c) 1 mM Fell and 2 mM Sn" Eº (Cel) = 1.41 V, reversible Eº (Fe) = 0.77 V, reversible Eº (Sn¹V) = 0.15 V, irreversible For (a) assume Eeq = 0.20 V and io/ilim = 0.001, for (c) assume io/ilim = 0.01.

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Chapter1: Chemical Foundations
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2. Sketch (as accurately as you can) steady state i vs E curves for solutions prepared from:
a) 1 mM SnV and 2 mM Ce
b) 1 mM Fell and 2 mM Celv
c) 1 mM Fell and 2 mM Sn"
Eº (Cel) = 1.41 V, reversible
Eº (Fe) = 0.77 V, reversible
Eº (Sn¹V) = 0.15 V, irreversible
For (a) assume Eeq = 0.20 V and io/ilim = 0.001, for (c) assume io/ilim = 0.01.
3. Draw concentration profiles for Cel in solution (b) from question 2 at:
a) 1.41 V
b) the anodic limiting current
c) 1.0 V
[Cell]bulk = 1 mM
Transcribed Image Text:2. Sketch (as accurately as you can) steady state i vs E curves for solutions prepared from: a) 1 mM SnV and 2 mM Ce b) 1 mM Fell and 2 mM Celv c) 1 mM Fell and 2 mM Sn" Eº (Cel) = 1.41 V, reversible Eº (Fe) = 0.77 V, reversible Eº (Sn¹V) = 0.15 V, irreversible For (a) assume Eeq = 0.20 V and io/ilim = 0.001, for (c) assume io/ilim = 0.01. 3. Draw concentration profiles for Cel in solution (b) from question 2 at: a) 1.41 V b) the anodic limiting current c) 1.0 V [Cell]bulk = 1 mM
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