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2. In the synthesis of peptides, carboxylic acids are condensed with amines in the present of a reagent such as dicyclohexylcarbodiimide (DCC) [Section 25.6]. a. Propose a mechanism for the following, using curved arrow notation. H₂N. Мон glycine H₂N. + OH Дон DCC H₂N. .OH OH H glycine gly-gly 1. Propose a detailed stepwise mechanism, using curved arrow notation, for the following. a. H+ N H2O, heat H b. N H 1. LiAlH4 (xs) 2. H₂O H OH Η + H

2. In the synthesis of peptides, carboxylic acids are condensed with amines in the present of a reagent such as dicyclohexylcarbodiimide (DCC) [Section 25.6]. a. Propose a mechanism for the following, using curved arrow notation. H₂N. Мон glycine H₂N. + OH Дон DCC H₂N. .OH OH H glycine gly-gly 1. Propose a detailed stepwise mechanism, using curved arrow notation, for the following. a. H+ N H2O, heat H b. N H 1. LiAlH4 (xs) 2. H₂O H OH Η + H

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2. In the synthesis of peptides, carboxylic acids are condensed with amines in the present of a reagent such as dicyclohexylcarbodiimide (DCC) [Section 25.6]. a. Propose a mechanism for the following, using curved arrow notation. H₂N. Мон glycine H₂N. + OH Дон DCC H₂N. .OH OH H glycine gly-gly
Transcribed Image Text:2. In the synthesis of peptides, carboxylic acids are condensed with amines in the present of a reagent such as dicyclohexylcarbodiimide (DCC) [Section 25.6]. a. Propose a mechanism for the following, using curved arrow notation. H₂N. Мон glycine H₂N. + OH Дон DCC H₂N. .OH OH H glycine gly-gly
1. Propose a detailed stepwise mechanism, using curved arrow notation, for the following. a. H+ N H2O, heat H b. N H 1. LiAlH4 (xs) 2. H₂O H OH Η + H
Transcribed Image Text:1. Propose a detailed stepwise mechanism, using curved arrow notation, for the following. a. H+ N H2O, heat H b. N H 1. LiAlH4 (xs) 2. H₂O H OH Η + H
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