2. In another cell, the potential of the copper metal, copper(II) ion electrode was found to be 0.442 V rela- tive to a silver metal, silver ion electrode, with the copper electrode being negative. Ag+, Ag a. If the potential of the silver, silver ion electrode, E is taken to be 0.000 V in oxidation or reduction, what is the value of the potential for the oxidation reaction, EC.Cu²+oxid? Ecell = Eoxid + Ered 0.00V=[ord #-0.442 Eoxid = 0.442 6,442 volts b. If E Ag.Ag red. equals +0.799V, as in standard tables of electrode potentials, what is the value of the potential of the oxidation reaction of copper, Ecu,Cu²+ oxid? 6.00V = Ex₁ +0.799 V 0.799 volts The student adds 6 M NH3 to the CuSO4 solution in this second cell until the Cu²+ ion is essentially all converted to Cu(NH3)42+ ion. The voltage of the cell, Ecell, goes up to 0.917 V and the Cu electrode is still negative. Find the residual concentration of Cu²+ ion in the cell. (Use Eq. 4.)

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2n(s) + Cu(May)
2. In another cell, the potential of the copper metal, copper(II) ion electrode was found to be 0.442 V rela-
tive to a silver metal, silver ion electrode, with the copper electrode being negative.
2n (aq)
си
Ag+, Ag
a. If the potential of the silver, silver ion electrode, E is taken to be 0.000 V in oxidation or
reduction, what is the value of the potential for the oxidation reaction, Eu.Cu²+oxid? Excell
Exid + Ered.
=
0.00V = [ord #-0.442
Foxid = 0.442
6,442 volts
b. If E
equals +0.799V, as in standard tables of electrode potentials, what is the value of the
potential of the oxidation reaction of copper, Eu.Cu²+oxid?
Ag.Ag red.
6.00V = Ex₁ +0.7991
0,799 volts
The student adds 6 M NH3 to the CuSO4 solution in this second cell until the Cu²+ ion is essentially
all converted to Cu(NH3)42+ ion. The voltage of the cell, Ecell, goes up to 0.917 V and the Cu electrode
is still negative. Find the residual concentration of Cu²+ ion in the cell. (Use Eq. 4.)
M
Transcribed Image Text:2n(s) + Cu(May) 2. In another cell, the potential of the copper metal, copper(II) ion electrode was found to be 0.442 V rela- tive to a silver metal, silver ion electrode, with the copper electrode being negative. 2n (aq) си Ag+, Ag a. If the potential of the silver, silver ion electrode, E is taken to be 0.000 V in oxidation or reduction, what is the value of the potential for the oxidation reaction, Eu.Cu²+oxid? Excell Exid + Ered. = 0.00V = [ord #-0.442 Foxid = 0.442 6,442 volts b. If E equals +0.799V, as in standard tables of electrode potentials, what is the value of the potential of the oxidation reaction of copper, Eu.Cu²+oxid? Ag.Ag red. 6.00V = Ex₁ +0.7991 0,799 volts The student adds 6 M NH3 to the CuSO4 solution in this second cell until the Cu²+ ion is essentially all converted to Cu(NH3)42+ ion. The voltage of the cell, Ecell, goes up to 0.917 V and the Cu electrode is still negative. Find the residual concentration of Cu²+ ion in the cell. (Use Eq. 4.) M
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