2. For the compound shown below, predict the expected IR and NMR data. Record the NMR data in the form (chemical shift, multiplicity, integration). You chemical shift values and IR absorption values only need to be a rough approximation. The first molecule is provided as an example. 4.0 ppm, q, 2H 1.4 ppm, t, 2H 1.2 ppm, t, 3H IR Data: C=O, 1740 cm-¹ 0.9 ppm, s, 9H 2.3 ppm, t, 2H Csp³-H, 2930-2990 cm-¹ Csp²-0, 1250 cm-¹ Csp³-0, 1050 cm-¹ H FO H IR Data:

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question
### Problem 2: NMR and IR Data Prediction

#### Task:
For the compound shown in the diagram, predict the expected IR and NMR data. Record the NMR data in the form of chemical shift, multiplicity, and integration. Chemical shift values and IR absorption values only need to be rough approximations. An example for the first molecule is provided.

#### NMR Data Example:
- **Chemical Shifts and Multiplicities:**
  - 4.0 ppm, quartet, 2H
  - 1.4 ppm, triplet, 2H
  - 0.9 ppm, singlet, 9H
  - 1.2 ppm, triplet, 3H
  - 2.3 ppm, triplet, 2H

#### IR Data:
- **Absorption Bands:**
  - C=O: 1740 cm<sup>-1</sup>
  - Csp<sup>3</sup>-H: 2930-2990 cm<sup>-1</sup>
  - Csp<sup>2</sup>-O: 1250 cm<sup>-1</sup>
  - Csp<sup>3</sup>-O: 1050 cm<sup>-1</sup>

#### Diagram Explanation:
- The molecular structure is shown with labeled hydrogen atoms indicating their expected NMR chemical shifts. Boxes are provided for students to fill in data for another molecule with the corresponding IR data section left blank for prediction.
Transcribed Image Text:### Problem 2: NMR and IR Data Prediction #### Task: For the compound shown in the diagram, predict the expected IR and NMR data. Record the NMR data in the form of chemical shift, multiplicity, and integration. Chemical shift values and IR absorption values only need to be rough approximations. An example for the first molecule is provided. #### NMR Data Example: - **Chemical Shifts and Multiplicities:** - 4.0 ppm, quartet, 2H - 1.4 ppm, triplet, 2H - 0.9 ppm, singlet, 9H - 1.2 ppm, triplet, 3H - 2.3 ppm, triplet, 2H #### IR Data: - **Absorption Bands:** - C=O: 1740 cm<sup>-1</sup> - Csp<sup>3</sup>-H: 2930-2990 cm<sup>-1</sup> - Csp<sup>2</sup>-O: 1250 cm<sup>-1</sup> - Csp<sup>3</sup>-O: 1050 cm<sup>-1</sup> #### Diagram Explanation: - The molecular structure is shown with labeled hydrogen atoms indicating their expected NMR chemical shifts. Boxes are provided for students to fill in data for another molecule with the corresponding IR data section left blank for prediction.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
IR Spectroscopy of Organic Molecules
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY