2. For each of the reactions below, give the structure(s) of the product(s), and be sure to indicate relative stereochemistry where appropriate. If more than one product is formed, indicate if they will be formed in equal amounts, or if one is expected to be the major product. If no reaction is expected to occur under the indicated conditions, then write “no reaction" or N.R. and explain why you would expect nothing to occur. (a) NaBHЗCN then H30* work up (b) NH2 Br2, NaOH, H2O (c) MCPBA then heat NME2 Me HH (d) i)Mel ii) Ag,0, heat Me H H (e) CH;NH2 LIAIHA Et,N then H* work-up NK (f) N2H4 Br DMF ELOH, reflux (aprotic, polar solvent)
2. For each of the reactions below, give the structure(s) of the product(s), and be sure to indicate relative stereochemistry where appropriate. If more than one product is formed, indicate if they will be formed in equal amounts, or if one is expected to be the major product. If no reaction is expected to occur under the indicated conditions, then write “no reaction" or N.R. and explain why you would expect nothing to occur. (a) NaBHЗCN then H30* work up (b) NH2 Br2, NaOH, H2O (c) MCPBA then heat NME2 Me HH (d) i)Mel ii) Ag,0, heat Me H H (e) CH;NH2 LIAIHA Et,N then H* work-up NK (f) N2H4 Br DMF ELOH, reflux (aprotic, polar solvent)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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