(e) NaOCI/ACOH N₂H, KOH, DMSO (c) 2 CH Br, Mg H₂O + (g) Sia ,BH H₂O₂, OH 2¹ (a) Br. (i) FeBr 3 (h) HgSO4 H₂O H₂SO4 (b) Br₂ (excess) 2 PCC Zn (Hg), HCI, H₂O (d) (f) CH,Br, Mg H₂O+

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please help with number 37
(e)
NaOCI/ACOH
N₂H, KOH,
DMSO
(c)
2 CH ,Br, Mg
H₂O +
(g)
Sia ,BH
H₂O₂, OH
2¹
(a)
Br.
(i)
FeBr 3
(h)
HgSO4 H₂O
H₂SO4
(b)
Br₂ (excess)
2
PCC
Zn (Hg), HCI,
H₂O
(d)
(f)
CH, Br, Mg
H₂O +
Transcribed Image Text:(e) NaOCI/ACOH N₂H, KOH, DMSO (c) 2 CH ,Br, Mg H₂O + (g) Sia ,BH H₂O₂, OH 2¹ (a) Br. (i) FeBr 3 (h) HgSO4 H₂O H₂SO4 (b) Br₂ (excess) 2 PCC Zn (Hg), HCI, H₂O (d) (f) CH, Br, Mg H₂O +
7) Alkyne hydrations (a and b) would provide two different "carbonyl compounds" and they
would yield the same product upon Clemmensen and Wolff-Kishner reductions (c and d),
respectively. Products of a and b would further lead to alcohols via Grignard and Reduction
reactions (e and f) whereas products of c and d would lead to the formation of aromatic
electrophilic brominations (g and h). Illustrate these reactions with suitable products below.
(0) NaOCVACOH
2 CH₂Br, Mg
H₂O +
(g)
Sia BH
50'0
H2O2, OH
(a)
N₂H 4 KOH,
4'
DMSO
(c)
HgSO4, H₂O
H₂SO4
(b)
Zn (Hg), HCl,
H₂O
(d)
Transcribed Image Text:7) Alkyne hydrations (a and b) would provide two different "carbonyl compounds" and they would yield the same product upon Clemmensen and Wolff-Kishner reductions (c and d), respectively. Products of a and b would further lead to alcohols via Grignard and Reduction reactions (e and f) whereas products of c and d would lead to the formation of aromatic electrophilic brominations (g and h). Illustrate these reactions with suitable products below. (0) NaOCVACOH 2 CH₂Br, Mg H₂O + (g) Sia BH 50'0 H2O2, OH (a) N₂H 4 KOH, 4' DMSO (c) HgSO4, H₂O H₂SO4 (b) Zn (Hg), HCl, H₂O (d)
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