2. For a Hydrogen atom, determine the allowed states corresponding to the principal quantum number n=2 and calculate the energies of these states.
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- Chapter 39, Problem 044 A hydrogen atom in a state having a binding energy (the energy required to remove an electron) of -1.51 eV makes a transition to a state with an excitation energy (the difference between the energy of the state and that of the ground state) of 10.200 eV. (a) What is the energy of the photon emitted as a result of the transition? What are the (b) higher quantum number and (c) lower quantum number of the transition producing this emission? Use -13.60 eV as the binding energy of an electron in the ground state. (a) Number Units (b) Number Units (c) Number Units3. Suppose an electron in a hydrogen atom is in a 2p state, and the radial wavefunction is (2a.)3/2 /3a. 2ao , where a, is the Bohr radius. (a) 2-axis? What possible angles might the angular momentum vector L make with the (b) What is the most probable radius (in terms of a,) at which the electron is found? (c) What is the expectation value of r in this state? Note: xe-"dx = 120. (p) S° x*e-dx = 23.91. What is the probability of finding such an electron between a, and oo? Note:1. Enumerate the microstates of p3. Determine the MS and ML values for each microstate. 2. On a table of possible MS and ML values, tally the microstates in no. 1 for a particular combination of MS and ML 3. Based on the table in no. 2, determine the atomic term symbols for the allowed atomic states of p3 resulting from the coupling of orbital and spin angular momentums. 4. Arrange the term symbols in no. 3 according to increasing energy.
- 3. Suppose an electron in a hydrogen atom is in a 2p state, and the radial wavefunction e 2ao, where a, is the Bohr radius. 1 is (2ао)3/2 VЗа. (а) What possible angles might the angular momentum vector L make with the Z-axis? (b) What is the most probable radius (in terms of a.) at which the electron is found? (c) What is the expectation value of r in this state? Note: S xe-"dx 120. (d) What is the probability of finding such an electron between a, and ∞? Note: ° x*e-"dx = 23.91.7. For the 3p and 3d states of hydrogen, show that (-) avg =1/1290. ao. n²